聚氯乙烯电纺纳米纤维化学改性法制备纳米银及其表征

Balqees Mohammed, H. Jawad
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摘要

本研究采用化学方法制备纳米银粒子(还原法)。在不同的摩尔浓度下,反应物质包括柠檬酸钠和硝酸银。以1:20的最佳摩尔浓度混合(柠檬酸钠:硝酸银)产生较小的平均尺寸。采用(DLS) Zetazaser仪测定银纳米粒子的Zeta电位和PDI。为了检查所生产的银纳米粒子的结构和成分,应用了x射线衍射和EDX技术。结果表明,该方法制备的纳米银颗粒稳定均匀,平均尺寸为58 nm, PDI系数为0.055。采用静电纺丝工艺,在严格的工作条件下,包括溶液的粘度、温度等参数,制备了不同粒径的银纳米粒子增强聚氯乙烯(PVC)纳米纤维。采用革兰氏阳性和革兰氏阴性微生物对银纳米颗粒制备的组织进行抑菌活性测试。根据研究结果,这两种细菌都被制造出来的组织有效地抑制到了99.99%的程度。
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Preparation and Characterization of Silver Nanoparticles by Chemical Method for Modification with Polyvinyl Chloride Electro Spun Nanofibers
In this study, a chemical procedure was used to produce nano-silver particles (reduction method). At different molar concentrations, reactive substances including sodium citrate and silver nitrate were employed. A smaller average size is produced by mixing (sodium citrate: silver nitrate) at an optimal molar concentration of (1:20). To determine the Zeta Potential and (PDI) of the generated silver nanoparticles, the (DLS) Zetazaser instrument was employed. To examine the structural and component of produced silver nanoparticles, X-ray diffraction and EDX techniques are applied. The outcomes showed that this approach generated stable, homogenous nano silver particles with an average size of 58 nm and a PDI factor of 0.055. The electrospinning process was used to create different nano-fiber diameters of poly vinyl chloride (PVC) nanofibers reinforced with silver nanoparticles from solution under strict working conditions, including solution parameters (viscosity, temperature). Gram-positive and gram-negative microorganisms were used to test the antibacterial activity of tissue generated with silver nanoparticles. According to the findings, both species of bacteria were effectively suppressed to a degree of 99.99 percent by the tissue that was created.
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