钼酸铵对硫酸锌(三)硫脲(ZTS)晶体力学性能的影响

K. Rathod, I. Patel, C. F. Desai, H. Desai
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引用次数: 0

摘要

三硫脲硫酸锌(ZTS)是一种引人注目的半有机非线性光学晶体。在本研究中,0.01N钼酸铵掺杂的ZTS晶体采用单扩散凝胶生长技术进行生长,在控制成核方面优于通常采用的溶液生长方法,因此更加完善。由于掺杂,观察到明显的形态学改变。利用傅里叶变换红外光谱(FTIR)对纯ZTS晶体和掺杂ZTS晶体的官能团进行了记录和鉴定。采用维氏硬度试验对掺杂后的硬度变化进行了研究。所观察到的硬度的增加可以归因于杂质硬化效应,因为发现由于掺杂剂的作用而增加。本文对所得结果进行了阐述和讨论。
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The Effect of Ammonium Molybdate on Mechanical Property of Zinc (tris) Thiourea Sulfate (ZTS) Crystal:A Novel NLO Crystal
Zinc tris-Thiourea sulfate (ZTS) is one of the notable semi organic non linear optical crystals. In the present investigation 0.01N Ammonium Molybdate doped ZTS crystal was grownusing single diffusion gel growthtechnique which has an advantage over normally employed solution growth method, in terms of controlled nucleation and hence better perfection. A significant morphological alteration was observed due to doping. The functional groups of pure and doped ZTS crystals were recorded and identified using Fourier Transform Infrared Spectroscopic (FTIR) analysis. A study on hardness variation due to doping was conducted using Vickers' Hardness Tests. The increase in hardness observed can be assigned to the impurity hardening effect as found to increased due to effect of dopant. The results obtained are elaborated and discussed in the paper.
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