原料及配比对磷酸镁水泥力学性能的影响

Yangzezhi Zheng , Yang Zhou , Xiaoming Huang , Haoyuan Luo
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引用次数: 6

摘要

磷酸镁水泥(MPC)胶凝材料是一种由氧化镁、磷酸盐缓凝剂和水发生一系列酸碱中和反应形成强度的磷酸盐水泥基材料,具有较高的早期强度,在路面修复领域具有广阔的应用前景。本文收集整理了近年来国内外关于磷酸镁胶凝材料力学性能影响因素的最新研究进展,并探讨了磷酸镁胶凝材料在机场工程中的应用可能性。磷酸盐的种类对反应产物的影响较大,铵盐反应产物的强度较高。硼砂是最常用的缓凝剂,其缓凝效果与硼镁比有关。然而,硼砂缓凝剂对MPC的强度有不利影响。在矿物掺合料对MPC性能的影响方面,粉煤灰、硅灰和偏高岭土作为常见的矿物掺合料,对MPC的力学性能有积极的影响,但三种材料对MPC强度的影响机理和程度略有不同;聚集体还可以通过形成骨架结构和减缓放热反应来改善MPC的体积稳定性和力学性能。在纤维增强MPC基体中,钢纤维的应用最为广泛,异型钢纤维与MPC基体的粘结性能高于直纤维;玄武岩纤维也被证明可以改善MPC体系的力学性能。
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Effect of raw materials and proportion on mechanical properties of magnesium phosphate cement

Magnesium phosphate cement (MPC) cementitious material is a phosphate cement-based material with strength formed by a serious of acid-base neutralization reactions among magnesium oxide, phosphate retarder and water, which has a high early strength and a broad application prospect in the field of pavement rehabilitation. This review collects and organizes the latest progress in the field of research on the influencing factors of mechanical properties of magnesium phosphate cementitious materials worldwide in recent years, and discusses the possibilities of application in airport engineering.

The type of phosphate has a great influence on the reaction products, and the strength of the reaction products of ammonium salt is higher. Borax is the most commonly used retarder, and the retarding effect is related to the ratio of boron to magnesium. However, borax retarders have an adverse effect on the strength of MPC. In terms of the influence of mineral admixtures on the properties of MPC, fly ash, silica fume and metakaolin, as common mineral admixtures, have a positive influence on the mechanical properties of MPC, but the mechanism and degree of the influence of the three materials on the strength of MPC are slightly different; Aggregates can also improve the volume stability and mechanical properties of MPC by forming skeleton structure and slowing down the exothermic reaction. In fiber reinforced MPC matrix, steel fiber is the most widely used and the bonding performance between special-shaped steel fiber and MPC matrix is higher than that of straight fiber; basalt fiber has also been proved to be used to improve the mechanical properties of MPC system.

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