{"title":"VIB基团二聚体:Mo2的新近红外电子态","authors":"D. Kraus, M. Lorenz, V. Bondybey","doi":"10.1039/B104063B","DOIUrl":null,"url":null,"abstract":"Laser vaporized Mo 2 is trapped in solid neon at 7 K and investigated by optical spectroscopy using a Fourier transform spectrometer. Besides the well known A 1 ← X 1 and a( 3 Λ) → X 1 transitions, a new NIR transition, denoted as a 3 → X 1 based on DFT calculations, is detected with the help of optical absorption and laser induced fluorescence spectroscopy. The visible A 1 ← X 1 transition of the mixed CrMo is observed for the first time in the gas phase using cavity ringdown absorption spectroscopy.","PeriodicalId":20106,"journal":{"name":"PhysChemComm","volume":"22 1","pages":"44-48"},"PeriodicalIF":0.0000,"publicationDate":"2001-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"21","resultStr":"{\"title\":\"On the dimers of the VIB group: a new NIR electronic state of Mo2\",\"authors\":\"D. Kraus, M. Lorenz, V. Bondybey\",\"doi\":\"10.1039/B104063B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Laser vaporized Mo 2 is trapped in solid neon at 7 K and investigated by optical spectroscopy using a Fourier transform spectrometer. Besides the well known A 1 ← X 1 and a( 3 Λ) → X 1 transitions, a new NIR transition, denoted as a 3 → X 1 based on DFT calculations, is detected with the help of optical absorption and laser induced fluorescence spectroscopy. The visible A 1 ← X 1 transition of the mixed CrMo is observed for the first time in the gas phase using cavity ringdown absorption spectroscopy.\",\"PeriodicalId\":20106,\"journal\":{\"name\":\"PhysChemComm\",\"volume\":\"22 1\",\"pages\":\"44-48\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"21\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"PhysChemComm\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/B104063B\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"PhysChemComm","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B104063B","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
On the dimers of the VIB group: a new NIR electronic state of Mo2
Laser vaporized Mo 2 is trapped in solid neon at 7 K and investigated by optical spectroscopy using a Fourier transform spectrometer. Besides the well known A 1 ← X 1 and a( 3 Λ) → X 1 transitions, a new NIR transition, denoted as a 3 → X 1 based on DFT calculations, is detected with the help of optical absorption and laser induced fluorescence spectroscopy. The visible A 1 ← X 1 transition of the mixed CrMo is observed for the first time in the gas phase using cavity ringdown absorption spectroscopy.
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