化学改性焦黄原麦麸吸附去除水溶液中的孔雀石绿染料

Dilli Dhami, P. L. Homagai
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引用次数: 4

摘要

研究了化学改性麦麸对孔雀石绿染料的吸附去除效果。通过炭化法对麦麸进行化学改性,使其焦化,再通过黄原法对其进行进一步改性。通过批量试验,同时研究了pH、浓度、接触时间等实验参数对焦化麦麸(CWB)和黄原酸麦麸(XWB)的影响。用紫外可见分光光度计测定吸附前后染料离子的浓度。当初始pH为4时,CWB和XWB的染料吸收率最高,但当吸附剂剂量为0.025g,搅拌速度为190 rpm时,XWB的去除率分别为98.45%和93.45%。验证了朗缪尔等温线的适用性。MG染料对CWB和XWB的吸附量分别为69 MG /g和112.9 MG /g。同样,动力学数据最适合拟二阶。因此,结果表明,与CWB相比,XWB可能是一种有吸引力的生物吸附剂,用于去除水溶液中的MG染料。
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Adsorptive Removal of Malachite Green Dye from Aqueous Solution Using Chemically Modified Charred and Xanthated Wheat Bran
Adsorptive removal of Malachite Green (MB) dye from aqueous solution using chemically modified Wheat Bran has been investigated. Wheat bran was chemically modified to charred through charring process and it was further modified to Xanthated through xanthation process. Batch experiments were carried out to study the experimental parameters such as effect of pH, effect of concentration and effect of contact time for both Charred Wheat Bran (CWB) and Xanthated Wheat Bran (XWB) simultaneously. The concentrations of dye ions before and after the adsorption were determined by using UV-Visible Spectrophotometer. The dye uptake was maximum for the initial pH of 4 for both CWB and XWB but the percentage removal for XWB was found to be effective in comparison with CWB i.e., 98.45% and 93.45% respectively with adsorbent dose of 0.025g and agitation speed of 190 rpm. The applicability of Langmuir isotherm was tested. The adsorption capacity of MG dye into CWB and XWB was found to be 69 mg/g and 112.9 mg/g, respectively. Similarly, the kinetic data best fitted for pseudo-second order. Hence, the result showed that XWB may be an attractive alternative for the removal of MG dye from aqueous solution in comparison to CWB as bioadsorbent.
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