可见光响应光催化剂CoPcS/TiO2/K2Ti4O9的制备、表征及光催化性能

Songtian Li, Yong-hua Cheng, Hang Gao
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引用次数: 1

摘要

采用溶胶-凝胶法制备CoPcS/TiO2光催化剂。采用浸渍法制备了CoPcS/TiO2/K2Ti4O9复合材料。在不同温度下对其进行了白炽化处理,并比较了改性效果。结果表明,样品在423K时的光吸收发生了明显的红移。光吸收宽度从紫外区向可见光区延伸,特别是在600 ~ 680 nm之间有较强的吸收。x射线衍射谱图显示,样品中TiO2仍保持锐钛矿晶体形态。在可见光照射下,以橙II为模拟污染物进行光催化降解实验。使橙ⅱ的脱色率大大提高。300分钟可达85%。
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Preparation, Characterization and Photocatalysis Properties of Visible Spectral Response Photocatalyst CoPcS/TiO2/K2Ti4O9
Photocatalyst CoPcS/TiO2 was prepared by sol-gel method. Composite CoPcS/TiO2/K2Ti4O9 was prepared by dipping. It was incandesced at various temperatures and modification effect was compared. The results showed that optical absorption of sample incandesce at 423K occurred significant red-shift. Light absorption width extended from ultraviolet region to visible region, especially there was an intensive absorption between 600 nm and 680 nm. X-ray diffraction spectrogram showed that TiO2 in sample still maintained anatase crystal form. Under the illumination of visible light, photocatalysis degradation experiment was taken with Orange II as simulated pollutants. Decoloration rate of Orange II was much improved. The rate can reach 85% in 300 minutes.
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