{"title":"磁性分子印迹聚合物化学修饰电极测定水样中17-β-雌二醇的研究","authors":"Daniela Nunes da Silva, A. Pereira","doi":"10.3390/electrochem3040053","DOIUrl":null,"url":null,"abstract":"The present work consisted of the development of an electrode based on carbon paste modified with magnetic molecularly imprinted polymer (CPE-MagMIP) for 17-β-estradiol (E2) detection. The incorporation of magnetic material (MagMIP) improved sensor performance, an increase of over 317%. The proposed method resulted in a linear response range from 0.5 to 14.0 μM, and the detection limit (LOD) and quantification limit (LOQ) were equal to 0.13 and 0.44 μM, respectively. Under optimized conditions, the developed sensor obtained satisfactory parameters in E2 determination in water samples, demonstrating selectivity, accuracy, and precision, making it a promising method for monitoring E2 in environmental samples.","PeriodicalId":11612,"journal":{"name":"Electrochem","volume":"61 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a Chemically Modified Electrode with Magnetic Molecularly Imprinted Polymer (MagMIP) for 17-β-Estradiol Determination in Water Samples\",\"authors\":\"Daniela Nunes da Silva, A. Pereira\",\"doi\":\"10.3390/electrochem3040053\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present work consisted of the development of an electrode based on carbon paste modified with magnetic molecularly imprinted polymer (CPE-MagMIP) for 17-β-estradiol (E2) detection. The incorporation of magnetic material (MagMIP) improved sensor performance, an increase of over 317%. The proposed method resulted in a linear response range from 0.5 to 14.0 μM, and the detection limit (LOD) and quantification limit (LOQ) were equal to 0.13 and 0.44 μM, respectively. Under optimized conditions, the developed sensor obtained satisfactory parameters in E2 determination in water samples, demonstrating selectivity, accuracy, and precision, making it a promising method for monitoring E2 in environmental samples.\",\"PeriodicalId\":11612,\"journal\":{\"name\":\"Electrochem\",\"volume\":\"61 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-12-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrochem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/electrochem3040053\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochem","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/electrochem3040053","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Development of a Chemically Modified Electrode with Magnetic Molecularly Imprinted Polymer (MagMIP) for 17-β-Estradiol Determination in Water Samples
The present work consisted of the development of an electrode based on carbon paste modified with magnetic molecularly imprinted polymer (CPE-MagMIP) for 17-β-estradiol (E2) detection. The incorporation of magnetic material (MagMIP) improved sensor performance, an increase of over 317%. The proposed method resulted in a linear response range from 0.5 to 14.0 μM, and the detection limit (LOD) and quantification limit (LOQ) were equal to 0.13 and 0.44 μM, respectively. Under optimized conditions, the developed sensor obtained satisfactory parameters in E2 determination in water samples, demonstrating selectivity, accuracy, and precision, making it a promising method for monitoring E2 in environmental samples.