膜生物反应器污染综合控制方法的发展

P. Gkotsis, M. Mitrakas, E. Peleka, Anastasios Zoumpoulis, Dimitrios Zampoulis
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引用次数: 0

摘要

膜生物反应器(mbr)处理废水最严重的缺点是膜污染,膜污染逐渐导致膜的渗透性降低,效率下降。这项工作是一个研究项目的一部分,该项目旨在开发一种综合的膜污染控制方法,使用特定的化学物质来增强引起污染的化合物的混凝和絮凝作用,从而减少膜表面的生物膜形成,并限制作为预处理步骤的污染率。为此,建立了一个采用可编程逻辑控制器(PLC)实现全自动操作的中试装置,并进行了试验。实验装置由四个单元组成:废水进料单元、生物反应器、膜(侧流)过滤单元和渗透收集单元。将合成废水(BOD=1000 mg/L)作为活性污泥(F/M=0.2 kg BOD/kg MLVSS∙d)的底物。通过在膜组件下方设置曝气器,使好氧池溶解氧(DO)在整个运行过程中保持在2 ~ 3 mg/L。过滤10分钟后,定期进行1分钟的反冲洗步骤。在加入商业混凝剂和复合混凝剂之前和之后,通过过滤性测试和SMP(可溶性微生物产物)浓度测量,对膜可逆和不可逆污染进行了预评估。膜污染导致处理成本增加,因为它能耗高,需要经常清洗和更换膜。由于MBR技术在过去几年的广泛应用,很明显,开发一种减轻膜污染的方法是至关重要的。目前的工作旨在开发一种集成技术,用于MBR系统中的膜污染控制,从而有助于可持续的废水处理。
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Development of an Integrated Methodology for Fouling Control in Membrane Bioreactors
The most serious drawback in wastewater treatment using membrane bioreactors (MBRs) is membrane fouling, which gradually leads to membrane permeability decrease and efficiency deterioration. This work is part of a research project that aims to develop an integrated methodology for membrane fouling control, using specific chemicals which enhance the coagulation and flocculation of compounds responsible for fouling, hence reducing biofilm formation on the membrane surface and limiting the fouling rate acting as a pre-treatment step. For this purpose, a pilot- scale plant with fully automatic operation achieved by means of programmable logic controller (PLC) has been constructed and tested. The experimental set-up consists of four units: wastewater feed unit, bioreactor, membrane (side-stream) filtration unit and permeate collection unit. Synthetic wastewater (BOD=1000 mg/L) was fed as the substrate for the activated sludge (F/M=0.2 kg BOD/kg MLVSS∙d). The dissolved oxygen (DO) concentration of the aerobic tank was maintained in the range of 2-3 mg/L during the entire operation by using aerators below the membrane module. Backflushing steps of 1 min were performed periodically after 10 min of filtration. Membrane reversible and irreversible fouling was pre-assessed in terms of filterability tests and SMP (soluble microbial product) concentration measurements conducted in mixed liquor samples before and after the addition of commercial and composite coagulants. Membrane fouling results in increased treatment cost, due to high energy consumption and the need for frequent membrane cleaning and replacement. Due to the widespread application of MBR technology over the past few years, it becomes clear that the development of a methodology to mitigate membrane fouling is of paramount importance. The present work aims to develop an integrated technique for membrane fouling control in MBR systems and, thus, contribute to sustainable wastewater treatment.
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