{"title":"超交联聚合物:综述","authors":"Jing Huang, Richard Turner","doi":"10.1080/15583724.2017.1344703","DOIUrl":null,"url":null,"abstract":"ABSTRACT Hypercrosslinked polymers (HCPs) represent a class of nanoporous materials with a wide range of practical and potential applications such as gas sorption and separation, heterogeneous catalysis, drug delivery, and chromatographic separation. First introduced by Davankov and Tsyurupa in the early 1970s, HCPs have developed rapidly over the past few decades. Mostly based on Friedel-Crafts chemistry, HCP materials can be prepared from the post-crosslinking of polystyrene-type precursors in their swollen state, or from the condensation of small building blocks. HCP materials manifest numerous important advantages, including moderate synthetic conditions, an enormous stockroom of inexpensive monomers, robust structures, and good thermal and chemical stabilities. This review article aims to provide an overview of recent publications on HCPs, and the emphasis is positioned on the synthetic approaches, theoretical studies, characterizations, structure-property relationships, and applications of these HCP materials.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"24 1","pages":"1 - 41"},"PeriodicalIF":11.1000,"publicationDate":"2018-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"154","resultStr":"{\"title\":\"Hypercrosslinked Polymers: A Review\",\"authors\":\"Jing Huang, Richard Turner\",\"doi\":\"10.1080/15583724.2017.1344703\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Hypercrosslinked polymers (HCPs) represent a class of nanoporous materials with a wide range of practical and potential applications such as gas sorption and separation, heterogeneous catalysis, drug delivery, and chromatographic separation. First introduced by Davankov and Tsyurupa in the early 1970s, HCPs have developed rapidly over the past few decades. Mostly based on Friedel-Crafts chemistry, HCP materials can be prepared from the post-crosslinking of polystyrene-type precursors in their swollen state, or from the condensation of small building blocks. HCP materials manifest numerous important advantages, including moderate synthetic conditions, an enormous stockroom of inexpensive monomers, robust structures, and good thermal and chemical stabilities. This review article aims to provide an overview of recent publications on HCPs, and the emphasis is positioned on the synthetic approaches, theoretical studies, characterizations, structure-property relationships, and applications of these HCP materials.\",\"PeriodicalId\":20326,\"journal\":{\"name\":\"Polymer Reviews\",\"volume\":\"24 1\",\"pages\":\"1 - 41\"},\"PeriodicalIF\":11.1000,\"publicationDate\":\"2018-01-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"154\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/15583724.2017.1344703\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Reviews","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/15583724.2017.1344703","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
ABSTRACT Hypercrosslinked polymers (HCPs) represent a class of nanoporous materials with a wide range of practical and potential applications such as gas sorption and separation, heterogeneous catalysis, drug delivery, and chromatographic separation. First introduced by Davankov and Tsyurupa in the early 1970s, HCPs have developed rapidly over the past few decades. Mostly based on Friedel-Crafts chemistry, HCP materials can be prepared from the post-crosslinking of polystyrene-type precursors in their swollen state, or from the condensation of small building blocks. HCP materials manifest numerous important advantages, including moderate synthetic conditions, an enormous stockroom of inexpensive monomers, robust structures, and good thermal and chemical stabilities. This review article aims to provide an overview of recent publications on HCPs, and the emphasis is positioned on the synthetic approaches, theoretical studies, characterizations, structure-property relationships, and applications of these HCP materials.
期刊介绍:
Polymer Reviews is a reputable publication that focuses on timely issues within the field of macromolecular science and engineering. The journal features high-quality reviews that have been specifically curated by experts in the field. Topics of particular importance include biomedical applications, organic electronics and photonics, nanostructures, micro- and nano-fabrication, biological molecules (such as DNA, proteins, and carbohydrates), polymers for renewable energy and environmental applications, and interdisciplinary intersections involving polymers.
The articles in Polymer Reviews fall into two main categories. Some articles offer comprehensive and expansive overviews of a particular subject, while others zero in on the author's own research and situate it within the broader scientific landscape. In both types of articles, the aim is to provide readers with valuable insights and advancements in the field of macromolecular science and engineering.