超交联聚合物:综述

IF 11.1 2区 化学 Q1 POLYMER SCIENCE Polymer Reviews Pub Date : 2018-01-02 DOI:10.1080/15583724.2017.1344703
Jing Huang, Richard Turner
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引用次数: 154

摘要

超交联聚合物(HCPs)是一类具有广泛实际和潜在应用的纳米多孔材料,如气体吸附和分离、多相催化、药物传递和色谱分离。由Davankov和Tsyurupa在20世纪70年代初首次提出,hcp在过去几十年中得到了迅速发展。HCP材料主要基于Friedel-Crafts化学,可以通过聚苯乙烯型前体在膨胀状态下的交联后制备,或者通过小型构建块的缩合制备。HCP材料具有许多重要的优点,包括适宜的合成条件、大量廉价单体、坚固的结构以及良好的热稳定性和化学稳定性。本文综述了近年来HCP材料的研究进展,重点介绍了HCP材料的合成方法、理论研究、表征、结构-性能关系及其应用。
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Hypercrosslinked Polymers: A Review
ABSTRACT Hypercrosslinked polymers (HCPs) represent a class of nanoporous materials with a wide range of practical and potential applications such as gas sorption and separation, heterogeneous catalysis, drug delivery, and chromatographic separation. First introduced by Davankov and Tsyurupa in the early 1970s, HCPs have developed rapidly over the past few decades. Mostly based on Friedel-Crafts chemistry, HCP materials can be prepared from the post-crosslinking of polystyrene-type precursors in their swollen state, or from the condensation of small building blocks. HCP materials manifest numerous important advantages, including moderate synthetic conditions, an enormous stockroom of inexpensive monomers, robust structures, and good thermal and chemical stabilities. This review article aims to provide an overview of recent publications on HCPs, and the emphasis is positioned on the synthetic approaches, theoretical studies, characterizations, structure-property relationships, and applications of these HCP materials.
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来源期刊
Polymer Reviews
Polymer Reviews 工程技术-高分子科学
CiteScore
24.80
自引率
0.80%
发文量
21
审稿时长
6 months
期刊介绍: Polymer Reviews is a reputable publication that focuses on timely issues within the field of macromolecular science and engineering. The journal features high-quality reviews that have been specifically curated by experts in the field. Topics of particular importance include biomedical applications, organic electronics and photonics, nanostructures, micro- and nano-fabrication, biological molecules (such as DNA, proteins, and carbohydrates), polymers for renewable energy and environmental applications, and interdisciplinary intersections involving polymers. The articles in Polymer Reviews fall into two main categories. Some articles offer comprehensive and expansive overviews of a particular subject, while others zero in on the author's own research and situate it within the broader scientific landscape. In both types of articles, the aim is to provide readers with valuable insights and advancements in the field of macromolecular science and engineering.
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