α-甘氨酸-硝酸胍水溶液中甘氨酸-硝酸胍单晶的研究。

D. Abraham, U. Sankar, S. Perumal, P. Selvarajan
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引用次数: 0

摘要

激光的发明使非线性光学领域的研究成为现实。用于通信和光信息处理的高性能电光开关元件是基于具有高非线性光学(NLO)特性的材料。从运输、计算到信息,高科技的发展和侵入都是以单晶形式的材料的可用性为基础的。采用α -甘氨酸和硝酸胍水溶液在室温下缓慢蒸发的方法,制备了半有机非线性光学单晶GLGN。单晶(GLGN)是一种半有机非线性光学(NLO)材料,采用慢速溶剂蒸发法制备。获得了尺寸达31 × 30 × 7 mm 3的光学质量良好的单晶。单晶x射线衍射(XRD)研究发现其存在带空间基团的单斜结构。利用光学吸收光谱、红外光谱和x射线衍射对晶体进行了表征,并对生长晶体的力学分析、差热分析(DTA)和热重分析(TGA)进行了研究。
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Studies of Glycine Guanidine Nitrate single crystals In the Aqueous Solution of α-Glycine and Guanidine Nitrate.
The field of nonlinear optics became practically a reality after the invention of laser. High Performance electro-optic switching elements for telecommunications and optical information processing are based on materials with high nonlinear optical (NLO) properties. The development and encroachment of high technology, from transportation, computation to information is based on the availability of materials in the form of single crystals. An semi organic nonlinear optical single crystal of Glycine Guanidine Nitrate (GLGN) has been grown by the aqueous solution of α -Glycine and Guanidine Nitrate by slow evaporation of the saturated solution at room temperature. Single crystal of (GLGN), an semi organic nonlinear optical (NLO) material, has been grown by slow solvent evaporation technique. Good optical quality single crystals with dimension up to 31 × 30 × 7 mm 3 are obtained. Single crystal X-ray diffraction (XRD) studies revealed the presence of monoclinic structure with space group. The crystals are characterized by optical absorption spectrum, FTIR and X-ray diffraction studies The mechanical and Differential thermal analysis (DTA) and thermo gravimetric analysis (TGA) study of the grown crystals are also investigated.
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