碳-碳多键的碳锌化反应

Organic Reactions Pub Date : 2015-09-18 DOI:10.1002/0471264180.OR087.03

G. Sklute, Hannah Cavender, I. Marek

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引用次数: 4

摘要

综述了近年来烯烃和炔烃的碳锌化研究进展。它包括非催化加成、催化加成和促进加成的有机锌衍生物在烯烃和炔烃的不饱和键上的加成。对于每一个反应，范围和局限性进行了讨论，特别强调机理和立体化学。并给出了实验条件和步骤。关键词:加法;烯烃;炔烃;carbozincation;碳-碳键形成;催化;organozinc

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Carbozincation Reactions of Carbon–Carbon Multiple Bonds

This review summarizes the field of carbozincation of alkenes and alkynes. It includes uncatalysed-, catalyzed-, and promoted-addition of orgnozinc derivatives across the unsaturated bond in alkenes and alkynes. For each reaction, the scope and limitations are discussed with specific emphasis on mechanism and stereochemistry. Experimental conditions and procedures are also presented. Keywords: Addition; alkenes; alkynes; carbozincation; carbon-carbon bond formation; catalysis; organozinc

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