二氧化碳还原和转化的人工光合作用

Hyomen Kagaku Pub Date : 2017-01-01 DOI:10.1380/jsssj.38.297
Y. Amao
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引用次数: 0

摘要

近年来,基于光还原或固定CO2的太阳能燃料或化工生产,所谓的“人工光合作用”受到了相当大的关注。因此,开发一种有效的催化剂将二氧化碳转化为有用的有机分子是可取的。二氧化碳还原和转化的生物催化剂是人工光合作用系统中有用的催化剂。本文介绍了可见光敏化剂和生物催化剂两种用于CO2还原和转化的人工光合系统。一种是利用可见光敏化剂和生物催化剂将CO2光还原为甲酸或甲醇的人工光合作用。另一种是以可见光敏化剂、新型电子载体分子和生物催化剂为原料,以CO2为原料形成碳-碳键的人工光合作用。
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Artificial Photosynthesis for Carbon Dioxide Reduction and Conversion
In recent years, solar fuel or chemical production based on the photoreduction or fixation of CO2, the so-called “artificial photosynthesis” has received considerable attention. Thus, the development of an effective catalyst for the conversion of CO2 to useful organic molecules is desirable. Biocatalysts for CO2 reduction and conversion are useful catalyst for the artificial photosynthesis system. In this review, two types of artificial photosynthesis systems for CO2 reduction and conversion consisting of the visible-light sensitizer and biocatalyst are introduced. One is the artificial photosynthesis with visible-light sensitizer and biocatalyst for CO2 photoreduction to formic acid or methanol. The other one is the artificial photosynthesis with visible-light sensitizer, and novel electron carrier molecule and biocatalyst for the carbon-carbon bond formation from CO2 as a feedstock.
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