复合材料火焰喷涂镀铝工艺研究

Q. Guo, Junjun Zhu, C. Li, P. Tang, C. Wen, Lan Liu, Tianze Wang, Yeqin Hu, Yingnan Zhao, M. Zhao, Yulong Feng, Hengyuan Xu, Haizhou Liu
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摘要

采用氧乙炔火焰喷涂技术在复合材料表面制备了铝涂层。采用H01-103H密封胶对热喷涂铝涂层进行密封。采用扫描电镜(SEM)、能谱仪(EDS)和力学试验机研究了添加和不添加H01-103H密封胶的铝涂层的表面形貌、相组成和结合强度。通过热冲击试验和低温冷却试验,考察了铝涂层的抗热冲击性能和抗冻性能。然后分别按照四探头测量原理和GJB 5239-2004测试导电性能和电磁屏蔽性能。结果表明:未添加H01-103H密封剂的铝涂层,其结合强度为7.36 MPa,表面孔隙率约为5.21%,且H01-103H密封剂可以填充孔隙,降低孔隙率,提高涂层的结合强度。涂层的主要成分为Al,氧含量仅为1.43%。火焰喷涂铝涂层表面电阻0.89 mΩ, 5-18 GHz的电磁屏蔽效能在35 dB以上,是电磁屏蔽利用的理想候选者。在50-200℃和- 30℃条件下,Al涂层保持完整、致密、无裂纹、剥落、分层,表现出良好的抗热震性和抗冻性。
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Research on the technology of flame spraying aluminum coating for composite material
Aluminum coating was prepared on composite material surface by using oxygen-acetylene flame spraying technology. The H01-103H sealants were used to seal the thermal sprayed aluminum coatings. The characteristics of the aluminum coatings with and without H01-103H sealant, including surface morphologies, phase composition, and bonding strength, were investigated by means of SEM, EDS, and mechanical testing machine. Thermal shock experiment and low temperature cooling test were also used to examine the thermal shock resistance and frost resistance of the Al coatings. Electrical conductivity and electromagnetic shielding properties were then tested according to four-probe measurement principle and GJB 5239-2004, respectively. The results showed that the bond strength was 7.36 MPa and the surface porosity was about 5.21% for Al coating without H01-103H sealant, in addition, the H01-103H sealants could fill into the pores, reducing the porosity and increasing the bond strength of the coating. Furthermore, the main component of the coating was Al, the oxygen content was only 1.43%. Flame sprayed aluminum coating, with surface electrical resistance 0.89 mΩ and 5–18 GHz electromagnetic shielding effectiveness above 35 dB, was an ideal candidate for electromagnetic shielding utilization. The Al coating remained intact, compact, no cracks, peeling, layering under 50–200°C and −30°C, which showed good thermal shock resistance and frost resistance.
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