I. Kizilcikli,, B. Ülküseven, Y. Daşdemir, B. Akkurt
{"title":"2/3 -甲酰基吡啶衍生的硫代氨基脲- S -烷基酯的Zn(II)和Pd(II)配合物","authors":"I. Kizilcikli,, B. Ülküseven, Y. Daşdemir, B. Akkurt","doi":"10.1081/SIM-120035948","DOIUrl":null,"url":null,"abstract":"Abstract Representative S‐methyl/ethyl‐4‐H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl2], [Pd(L)Cl2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1H NMR spectra. The multidentate S‐alkyl thiosemicarbazones coordinate as mono‐, bi‐, or tridentate ligands depending on the types of the alkyl moiety and metal ion.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"3 1","pages":"653 - 665"},"PeriodicalIF":0.0000,"publicationDate":"2004-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"31","resultStr":"{\"title\":\"Zn(II) and Pd(II) Complexes of Thiosemicarbazone‐S‐alkyl Esters Derived from 2/3‐Formylpyridine\",\"authors\":\"I. Kizilcikli,, B. Ülküseven, Y. Daşdemir, B. Akkurt\",\"doi\":\"10.1081/SIM-120035948\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Representative S‐methyl/ethyl‐4‐H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl2], [Pd(L)Cl2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1H NMR spectra. The multidentate S‐alkyl thiosemicarbazones coordinate as mono‐, bi‐, or tridentate ligands depending on the types of the alkyl moiety and metal ion.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"3 1\",\"pages\":\"653 - 665\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"31\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-120035948\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-120035948","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Zn(II) and Pd(II) Complexes of Thiosemicarbazone‐S‐alkyl Esters Derived from 2/3‐Formylpyridine
Abstract Representative S‐methyl/ethyl‐4‐H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl2], [Pd(L)Cl2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1H NMR spectra. The multidentate S‐alkyl thiosemicarbazones coordinate as mono‐, bi‐, or tridentate ligands depending on the types of the alkyl moiety and metal ion.