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引用次数: 1
摘要
决定超级电容器性能的主要因素之一是通过促进表面依赖的电化学反应过程来发展纳米层状结构。碳基纳米材料,特别是石墨烯,由于其优异的性能,包括高导电性和大比表面积,在包括超级电容器在内的电荷和电源领域引起了极大的兴趣。本文研究了聚四氟乙烯(PTFE)粘结剂配比(1、5、10和15 wt. %)对石墨烯超级电容器电化学性能的影响。此外,还提出了采用低成本浆料技术制备石墨烯电极的简便、可扩展方法。从所进行的实验工作中发现,制备的石墨烯电极在超级电容器应用中表现出优异的电化学性能,其比重量电容高达373 F g−1。此外,石墨烯电极具有优异的循环稳定性,在10,000次充放电循环后具有99%的比电容保持率,因此有望成为长效超级电容器。经过深思熟虑的研究结果为开发具有成本效益的石墨烯基材料生产储能装置提供了知识基础。
Effect of Polytetrafluoroethylene Binder Content on Gravimetric Capacitance and Life Cycle Stability of Graphene Supercapacitor
One of the major elements in determining the supercapacitor performance is the development of a nano-layered structure through facilitating the surface-dependent electrochemical reaction processes. Carbon-based nanomaterials especially graphene, has attracted tremendous interest in electrical charge and power sources including supercapacitor because of their exceptional properties, which include high conductivity and large specific surface area. In this paper, the effect of polytetrafluoroethylene (PTFE) binder ratio (1, 5, 10, and 15 wt. %) on the electrochemical performance of graphene supercapacitor are evaluated. In addition, the facile and scalable preparation of graphene electrodes by using low-cost slurry technique is proposed. From the conducted experimental works, it was found that the fabricated graphene electrodes exhibit superior electrochemical properties for supercapacitor applications with a specific gravimetric capacitance of up to 373 F g−1. Moreover, the graphene electrode presented excellent cyclic stability with 99 % specific capacitance retention after 10,000 charge/discharge cycles hence promising for long‐lasting supercapacitors. The outcomes from the deliberated study serve as the basis of knowledge in the development of a cost-effective graphene-based materials production for energy storage devices.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.