模拟天然气输送条件下低碳钢环的腐蚀评价

Jewad K. Shneine
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摘要

在2l玻璃高压灭菌器中研究了天然气生产条件下钢环(钢管)的腐蚀。钢管轴向构造,腔径比为3×1 mm,在玻璃高压灭菌器中以6m/s的流速和5bar的CO2流量暴露于CO2饱和氯化物溶液中4天。研究了温度、氯离子浓度、缓蚀剂配比等因素的影响。在此基础上,对不同条件下的去除质量、表层质量和腐蚀速率进行了评价。并对Fe2+浓度和pH值进行了评价。利用偏光显微镜在不同倍率下对试样的腐蚀程度进行了评价。结果表明,加入Dodisclae V3962缓蚀剂后,受高温和高氯化物浓度影响的高腐蚀速率明显降低。形成固定的表面层质量可能是高缓蚀性的原因。(DOI: 10.22401 / JUNS.20.3.08)
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Evaluation the Corrosion of Mild Steel Rings in Simulated Conditions of Natural Gas Transportation
Corrosion of steel rings (steel tubes) under natural gas production conditions has been studied in a 2 L glass autoclave. Steel tubes, axially constructed with cavities of aspect ratios 3×1 mm, were exposed to CO2 saturated chloride salt solutions in a glass autoclave for 4 days at a flow rate of 6m/s and CO2 flow of 5 bar. Effect of temperature, chloride ion concentration, and inhibitor ratio has been studied. Accordingly, removal mass, surface layer mass and the corrosion rate were evaluated at different conditions. Fe2+ concentrations and pH values were also evaluated. The corrosion degree of the tested samples is assessed by polarizing microscope at different magnification values. Results showed that high corrosion rates affected by high temperatures and high chloride concentrations, have been particularly reduced by addition of Dodisclae V3962 inhibitor. Formation of a fixed surface layer mass might be the reason for the high corrosion inhibition. [DOI: 10.22401/JUNS.20.3.08]
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