Qi Chen, Huijie Lun, Yong-Hong Li, Shu Li, Bei-Bei Li, Xudong Zhang, Yamin Li
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Hydrothermal Synthesis and Structural Characterization of a Three-Dimensional Coordination Polymer on Ag(I)
A new coordination polymer [Ag3(1,2,4-btc)]n (1) (1,2,4-H3btc = 1,2,4-benzenetricarboxylate) has been synthesized by hydrothermal method and characterized by X-ray single crystal diffraction, elemental analysis, IR spectrum, and TGA. Compound 1 exhibits a 3D network consisting of the 2D layer connected by the ligand 1,2,4-btc3−, which adopts a new coordination mode. Moreover, blue fluorescence at 480 nm emission was observed under 320 nm excitation.
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