SBL用Y3Fe5O12-MWCNTs复合材料的合成与表征

M. Akhtar, N. Yahya, Nadeem Nasir, M. Kashif
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引用次数: 1

摘要

海底测井是一项正在实施的深部目标勘探新技术。在海底测井中,电磁波震级对油气储层的探测是非常重要的,也是一个挑战。采用磁性给料器(Y3Fe5O12加和不加MWCNTs)的新型Al发射机在船用规模化储罐中增强磁场强度。实验在海洋实验室规模的水槽中进行,以模拟真实的海底环境。采用溶胶-凝胶-自燃混合法制备了带和不带多壁碳纳米管的Y3Fe5O12。分别在550°C、750°C和1050°C下对样品进行烧结,获得所需的石榴石纳米颗粒特性。采用XRD、RAMAN、FESEM和阻抗网络分析仪对添加和不添加MWCNTs的Y3Fe5O12样品进行了表征。x射线衍射结果表明,在烧结温度为1050℃时,Y3Fe5O12相呈现最佳相态。采用溶胶-凝胶-自燃混合法制备了粒径在70 ~ 110 nm之间的纳米颗粒。在1050℃的烧结温度下,拉曼光谱结果也证实了Y3Fe5O12的石榴石结构。采用场发射扫描电镜(FESEM)观察了Y3Fe5O12加入和不加入MWCNTs复合材料的形貌。磁性表征结果表明,在1050℃下,Y3Fe5O12 - MWCNTs复合材料具有较高的初始磁导率(33.302)和高q因子(55.104),同时还研究了Y3Fe5O12 - MWCNTs复合材料的低损耗因子(0.0003)。结果表明,使用Y3Fe5O12-MWCNTs聚合物复合材料环面作为磁性给料剂,磁场强度提高210%。
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Synthesis and characterizations of Y3Fe5O12-MWCNTs composites for SBL application
Sea bed logging is a new technology being implemented for deep target exploration. In seabed logging, the magnitude of electromagnetic (EM) wave for detection of hydrocarbon reservoir is very important and still remained challenge. New Al transmitter with (Y3Fe5O12 with and without MWCNTs) magnetic feeders was used in a marine scaled tank to enhance the magnetic field strength. Experiments were done in marine lab scale tank to replicate the real seabed environment. Y3Fe5O12 with and with out multiwall carbon nano tubes (MWCNTs) were synthesized by using sol gel-self combustion hybrid method. Samples were sintered at 550°C, 750°C and 1050°C to get the required characteristics of the garnet nanoparticles. Y3Fe5O12 samples with and without MWCNTs were characterized by using XRD, RAMAN, FESEM and Impedance network analyzer. X-ray diffraction results revealed that the best Y3Fe5O12 phase was appeared at the sintering temperature of 1050°C. Nanoparticles sizes ranging from 70 to 110 nm were obtained by using sol gel-self combustion hybrid method. Raman results also demonstrate the confirmation of garnet structure of Y3Fe5O12 at sintering temperature of 1050°C. Field emission scanning electron microscopy (FESEM) was used to see the morphology of Y3Fe5O12 with and with out MWCNTs composites. Magnetic characterization results illustrates that Y3Fe5O12 with MWCNTs at 1050°C has higher Initial permeability (33.302) and high Q-factor (55.104), where as low loss factor (0.0003) was also investigated for Y3Fe5O12 — MWCNTs composites. It was observed that by using Y3Fe5O12-MWCNTs polymer composites toroid as magnetic feeders resulted 210% increase in magnetic field strength.
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