含丙烯酮和2-烷氧基乙醇二元混合物在303.15K, 308.15K, 313.5 k和318.15K下的热力学过量性质和FTIR光谱研究

N. Devi, N. B. Rao, M. RadhaSirija, D. Ramachandran
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引用次数: 2

摘要

在303.15K至318.15K的整个组成范围内,在大气压0.1MPa下,测定了丙烯酮(PPH)与2-烷氧基乙醇[2-甲氧基乙醇,2-乙氧基乙醇,2-丁氧基乙醇]二元混合物的密度ρ,粘度η和声速。利用所得实验数据计算了超摩尔体积V E、超声速U E、声阻抗Z、超声阻抗Z、等熵压缩率KS、超等熵压缩率KS、分子间自由长度Lf、分子间自由长度Lf、分子间自由长度Lf、分子间自由长度f、分子间自由长度f、分子间自由长度f等声学参数。计算了粘度偏差Δη,并将计算结果与Redlich Kister方程拟合,估计了实验数据与计算数据之间的二元系数和标准差。在不同浓度下,对上述二元混合物进行了FTIR分析,以证实氢键的存在。
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Thermodynamic Excess Properties and FTIR Spectroscopic Studies of Binary Mixtures Containing Propiophenone and 2- Alkoxy Ethanolsat Temperatures 303.15K, 308.15K, 313.5Kand 318.15K
Densities ρ, viscosities η and ultrasonic speeds of soundof binary mixtures of Propiophenone (PPH) with 2-Alkoxy Ethanols [2-Methoxy Ethanol, 2-Ethoxy Ethanol, 2-Butoxy Ethanol] have beenmeasured over the entire composition range from 303.15K to 318.15K and at atmospheric pressure 0.1MPa. Theworked out experimental data has been used to calculate various acoustical parameters like excess molar volume V E , excess ultrasonic velocity U E , acoustic impedance Z, excess acoustic impedance (Z E ), isentropic compressibility KS,excess isentropic compressibility Ks , intermolecular free length Lf,excess intermolecular free-length (Lf ), deviation in viscosity Δη were calculatedand the computed results were fitted with the Redlich Kister equation to estimate the binary coefficients and standard deviation between experimental and calculated data.At different concentrations, FTIR analysis has been done for the above binary mixtures to confirm the hydrogen bonding presence.
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