用电测量和XRF分析研究了不同LiCl掺杂下聚苯胺的性质

F. Chaqmaqchee, A. Baker
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引用次数: 3

摘要

采用化学聚合法制备聚苯胺聚苯胺样品。通过测量不同浓度氯化锂的直流电导率,研究了复合材料中电荷输运的机理。结果表明,它们的活化能随LiCl浓度的增加而降低,电导率在15% wt时增加。此外,用x射线荧光XRF分析了聚苯胺元素与LiCl浓度的关系。XRF检测到的阳性元素有Cl、Kr、so3、al2o3、sio2和ZrO 2。XRF数据显示相对系统误差通常与浓度无关。通过比较XRF数据与不同的LiCl wt.%来确定准确度。
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Study and Characterization of Polyaniline at Various Doping of LiCl wt.% Using Electrical Measurements and XRF Analysis
Polyaniline PANI samples were synthesized via chemical polymerization method. The mechanism of charge transport in these composites has been studies by measuring the DC conductivity at various lithium chloride LiCl wt.%. It shows that their activation energy decreases with increasing LiCl concentration and thus, the conductivity increases at 15 %wt. In addition, X-ray Fluorescence XRF was used to analysis the elements of PANI regarding to LiCl concentration. The elements positively detected by the XRF are Cl, Kr, SO 3 , Al 2 O 3 , SiO 2 , and ZrO 2 . The XRF data show a relative systematic error typically independent of the concentration. The accuracy is determined by comparing the XRF data with various LiCl wt.%.
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