环氧树脂-烯丙基瓜尔胶复合材料的力学和结构性能

Gopal Arora, A. Gupta
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摘要

瓜尔胶是从瓜尔豆胚乳中提取的一种非离子型多糖。瓜尔胶及其衍生物是水溶性亲水性多糖,需要进行疏水改性以增加其在聚合物基质中的相容性。本文研究了烯丙基改性瓜尔胶(AGG)及其环氧树脂复合材料的合成。在0.5-4.5 wt%范围内,对所制备的复合材料的力学性能进行了评价。利用万能试验机(UTM)和扫描电子显微镜(SEM)对复合材料的力学性能和结构性能进行了研究。以烯丙基瓜尔胶为填料,采用铸造工艺制备了环氧复合材料。聚合物与填料的相互作用随填料含量的变化而变化。当AGG浓度为0.5%时,拉伸强度可提高13%。断裂伸长率与复合材料的抗拉强度数据相反。观察到的力学性能与复合材料的断裂形貌相关。良好的分散性,即聚合物与填料的相互作用,提高了复合材料的抗拉强度,而不良的相互作用则降低了复合材料的抗拉强度。据报道,0.5%浓度的烯丙基瓜尔胶(AGG1)可获得最大拉伸强度。当填料浓度为3%时,agg2基环氧复合材料断裂伸长率的最大增幅为25%。
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Mechanical and Structural Properties of Epoxy Resin-Allyl Guar Gum Composites
Guar gum is a non-ionic polysaccharide extracted from the endosperm of Cyamopsistetragonalobus. Guar gum and its derivatives are water-soluble hydrophilic polysaccharides, and hydrophobic modification is required to increase its compatibility in a polymer matrix. The present study investigates the synthesis of allyl-modified guar gum (AGG) and epoxy resin composites. The mechanical properties of the prepared composites with varying concentrations of filler (allyl guar gum) in the range of 0.5-4.5 wt% have been evaluated. The mechanical and structural properties of the prepared composites have been investigated using Universal Testing Machine (UTM) and Scanning Electron Microscope (SEM), respectively. The epoxy composites were prepared by casting technique using allyl guar gum as the filler. The polymer-filler interactions varied with the contents of the filler. The tensile strength was found to be enhanced up to 13% at 0.5% concentration of AGG. The % elongation at break values followed an opposite trend as compared to the tensile strength data of the composites. The observed mechanical properties have been correlated with the fracture morphology of the composites. A better dispersion, that is, polymer-filler interactions, improved the tensile strength of composites, while poor interactions declined the tensile strength. It is reported that max tensile strength can be obtained at 0.5% concentration of allyl guar gum (AGG1). The maximum increase in % elongation at break was 25% for AGG2-based epoxy composite at 3% of filler concentration.
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