慢蒸发法制备丝氨酸醋酸锌有机非线性光学材料的合成、晶体生长及表征

R. Sakunthaladevi
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引用次数: 0

摘要

以水为溶剂,采用缓慢蒸发法制备了光学性能优良的丝氨酸醋酸锌单晶。通过单晶XRD研究得到了电池参数的取值。通过FTIR研究确定了SZA中存在的各种功能基团。通过紫外-可见-近红外光谱研究分析了生长晶体的光学行为,发现材料SZA在可见光区域具有广泛的透明度。维氏显微硬度研究揭示了生长材料的硬化性质。热重分析和差热分析证实了SZA的热稳定性。采用Kurtz-Perry粉末法测定了生长晶体的NLO活性。版权所有©VBRI出版社。
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Synthesis, Crystal Growth and Characterization of Serine Zinc Acetate an Organic Nonlinear Optical material by Slow Evaporation Method
Optically good quality single crystal of Serine Zinc Acetate (SZA) was grown by the method of slow evaporation and using a solvent of water. The value of cell parameters was obtained by single crystal XRD study. The various functional groups of molecules present in SZA were identified from FTIR studies. The optical behaviour of the grown crystal was analysed through UV-VIS-NIR spectral studies and the material SZA was found to have wide range of transparency in the visible region. The Vickers micro hardness study revealed the hardening nature of the grown material. Thermal stability of SZA was confirmed using thermo gravimetric and differential thermal analyses. The NLO activity of the grown crystal was tested by Kurtz-Perry powder technique. Copyright © VBRI Press.
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