金属纳米粒子与染料的活性等离子体耦合

M. Abdelaziz, M. Hedayati, M. Elbahri
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引用次数: 0

摘要

光活性分子和金属纳米粒子在透明衬底上的随机排列的等离子体耦合被证明。观察到紫外辐射对分子的触发使金纳米粒子的等离激元共振发生位移。实际上,在紫外光照射下,覆盖有掺杂聚苯乙烯的螺旋恶嗪薄层的金属纳米团簇在透射光谱中发生了共振倾角的分裂,光致分裂倾角之间的波长差可达80nm。观察的起源归因于激活的分子共振与纳米粒子的局部等离子体激元的耦合。粒子与分子间耦合动态控制的可能性为等离子体系统在新型光电器件中的应用铺平了道路。
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Active plasmonic coupling of metallic nanoparticles with dye
The plasmonic coupling of photoactive molecules and random arrangements of metal nanoparticles on a transparent substrate is demonstrated. It was observed that the triggering of the molecules by UV irradiation shift the plasmon resonance of the gold nanoparticles. In fact, UV irradiation of metal nanoclusters covered with thin layer of Spirooxazine doped polystyrene split the resonance dip in transmission spectra in which the wavelengths difference between the photo-induced divided dips can reach up to 80nm. The origin of the observation attributed to the coupling of the activated molecule resonance with that of the localized plasmon of the nanoparticles. The possibility of the dynamic control of the coupling between the particles and molecules can pave the way for application of plasmonic system in new optoelectronic devices.
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