J. Qin, Na Lei, H. Ding, Ya-Ping Liu, Yong-Peng Xu, S. Qian
{"title":"基于3,5-二(吡啶-2-基)-4-氨基-1,2,4-三唑的Cd(II)， Ag(I)配合物的合成、晶体结构和荧光性质","authors":"J. Qin, Na Lei, H. Ding, Ya-Ping Liu, Yong-Peng Xu, S. Qian","doi":"10.1080/15533174.2015.1004417","DOIUrl":null,"url":null,"abstract":"Two d10 complexes [Cd(abt)I2(H2O)] (1) and [Ag2(abt)2]·2(CF3SO3) (2), (abt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been obtained and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Complex 1 is mononuclear and Cd(II) center is five coordinated, while complex 2 possesses a dinuclear structure with coordination number 4 for Ag(I) center. Solid-state fluorescence spectra of 1, 2, and abt were investigated at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Syntheses, Crystal Structures, and Fluorescence Properties of Cd(II), Ag(I) Complexes Based on 3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole\",\"authors\":\"J. Qin, Na Lei, H. Ding, Ya-Ping Liu, Yong-Peng Xu, S. Qian\",\"doi\":\"10.1080/15533174.2015.1004417\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two d10 complexes [Cd(abt)I2(H2O)] (1) and [Ag2(abt)2]·2(CF3SO3) (2), (abt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been obtained and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Complex 1 is mononuclear and Cd(II) center is five coordinated, while complex 2 possesses a dinuclear structure with coordination number 4 for Ag(I) center. Solid-state fluorescence spectra of 1, 2, and abt were investigated at room temperature.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1004417\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1004417","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Syntheses, Crystal Structures, and Fluorescence Properties of Cd(II), Ag(I) Complexes Based on 3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole
Two d10 complexes [Cd(abt)I2(H2O)] (1) and [Ag2(abt)2]·2(CF3SO3) (2), (abt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been obtained and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Complex 1 is mononuclear and Cd(II) center is five coordinated, while complex 2 possesses a dinuclear structure with coordination number 4 for Ag(I) center. Solid-state fluorescence spectra of 1, 2, and abt were investigated at room temperature.
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