漆石的宝石学特征

Guo Jie, Liao Renqing, Zheng Qiuju
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摘要

Painite是一种非常罕见的宝石品种,其宝石学特征很少报道。本文采用常规宝石学仪器、红外光谱仪、拉曼光谱仪、EDS能谱仪及光致发光光谱技术对该宝石石样品进行检测,以提供该品种的宝石学数据,提高检测效率。结果表明,颜料石的折射率超出了宝石折光计的测量范围,二色性明显。在棱镜分光镜下可以看到典型的吸收光谱。在LW紫外光下表现为惰性,在SW紫外光下表现为中~强黄绿色荧光。密度为3.89±0.02 g/cm3,莫氏硬度为7-8,有壳体断裂。红外光谱和拉曼光谱结果表明,样品的特征峰与B-O、Al-O、Ca-O和Zr-O的振动有关,其中[BO3]3-和[BO4]5-共存。光致发光光谱证实了样品中存在电子空穴核。紫外可见吸收光谱显示样品的吸收峰与Ti、V、Fe的叠加有关。能谱仪测定的样品中主要元素与画石分子式一致。
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Gemmological Characteristic of Painite
Painite belongs to a very rare gem variety, and its gemmological characteristics are rarely reported.In this paper, the painite samples were tested by conventional gemmological intruments, infrared spectrometer, Raman spectrometer, EDS energy spectrometer and photoluminescence spectrum technology in order to provide gemmological data of the variety, and improve the detection efficiency. The results showed that the refractive index of painite is beyond the measurement range of gem refractometer and dichroism is obvious. The typical absorption spectrum can be seen under prism spectroscope. It showed inert under LW ultraviolet lamp, and medium to strong yellow green fluorescence under SW ultraviolet lamp. The density is 3.89±0.02 g/cm3, and its Mohs hardness is 7-8 with shell fracture.The results of IR and Raman spectra showed that the characteristic peaks of the sample were related to the vibration of B-O, Al-O, Ca-O and Zr-O, where [BO3]3- and [BO4]5- coexist. The photoluminescence spectra confirmed the existence of electron hole core in the sample. UV-Vis absorption spectra showed that the absorption peaks of the sample were related to the superposition of Ti, V and Fe. The main elements of the sample measured by EDS spectrometer are consistent with the painite formula.
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