伽马射线对脉冲激光烧蚀制备银纳米粒子的影响研究

Mohammed Al-Maher, Najwa al-Barhawi, M. Al-Jubbori
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摘要

本研究采用液体激光烧蚀(PLAL)法制备了两种能量(540和700)mJ,脉冲数分别为(100,200,300和400)个脉冲的银纳米颗粒。将制备好的样品分为三组,第一组样品保持不辐照,第二组和第三组样品分别以7.5和11 KGy两种剂量的Co-60源辐照。通过一系列的测量和研究,从透射电子显微镜(TEM)上观察到,在激光能量(540)mJ、脉冲数(400)下制备的纳米颗粒呈球形,而在激光能量(700)mJ、脉冲数(400)下制备的纳米颗粒呈纳米棒状。研究了不同制备条件下伽马辐照对纳米粒子光学性能的影响,其表现为脉冲和激光能量的变化。结果表明,随着辐照剂量的增加,吸光度峰有所增加。透射电镜(TEM)图像显示,我们得到了球形的纳米颗粒。在(540)mJ激光能量下,制备的银纳米粒子的平均直径在(30-40)nm范围内。
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Study the effect of gamma ray on silver nanoparticles prepared by pulse laser ablation in liquid technique (PLAL)
Silver nanoparticles in this study were prepared using the method of laser ablation in liquids (PLAL) at two energies (540 and 700) mJ and the count of pulses were (100,200,300 and 400) pulse . The prepared samples were divided into three groups: the first group of the samples were kept as they are without any irradiation but the second and third group were irradiated by Co-60 source with two amount of doses (7.5 and 11) KGy respectively . A series of measurements and studies were done , and from the pictures of Transmitted Electron Microscope (TEM) , it was observed that the prepared nanoparticles at laser energy (540) mJ with pulses count (400) pulse were spherical but the prepared nanoparticles at laser (700) mJ with pulses cont (400) pulse were nano rods shape. The gamma irradiation effect was studied through its effect on the optical properties of the nanoparticles at different preparation conditions , represented by a change in the pulses and the energy of the laser used. The results showed that there was an increase the absorbance peaks when increasing the irradiated dose. The (TEM) image showed we get spherical nanoparticles in shape and nano composition. The average diameter of the prepared silver nanoparticles at (540) mJ laser energy in the range of (30-40) nm.
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