{"title":"三(1,10-菲罗啉)锰(II)三高氯酸四乙基铵(Et4N)[Mn(phen)3](ClO4)3的合成与晶体结构","authors":"Cheng-Bing Ma, Changneng Chen, Qiutian Liu","doi":"10.2116/ANALSCIX.24.X33","DOIUrl":null,"url":null,"abstract":"The title complex was serendipitously obtained by reacting imidazole-4,5-dicarboxylic acid, tetraethylammonium hydroxide, 1,10-phenanthroline, and manganese(II) perchlorate hexahydrate in ethanol-water mixed solvent. It crystallizes in the monoclinic system, space group Cc with a = 24.8043(6), b = 8.7973(2), c = 24.2475(2)A, β = 118.844(1)°, V = 4634.6(2)A3 and Z = 4. A most noteworthy structural feature is that two counterions, namely Et4N+ and ClO4- cocrystallize in the crystal lattice.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"72 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Crystal Structure of Tetraethylammonium Tris(1,10-phenanthroline)manganese(II) triperchlorate (Et4N)[Mn(phen)3](ClO4)3\",\"authors\":\"Cheng-Bing Ma, Changneng Chen, Qiutian Liu\",\"doi\":\"10.2116/ANALSCIX.24.X33\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title complex was serendipitously obtained by reacting imidazole-4,5-dicarboxylic acid, tetraethylammonium hydroxide, 1,10-phenanthroline, and manganese(II) perchlorate hexahydrate in ethanol-water mixed solvent. It crystallizes in the monoclinic system, space group Cc with a = 24.8043(6), b = 8.7973(2), c = 24.2475(2)A, β = 118.844(1)°, V = 4634.6(2)A3 and Z = 4. A most noteworthy structural feature is that two counterions, namely Et4N+ and ClO4- cocrystallize in the crystal lattice.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"72 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X33\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X33","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
标题配合物是由咪唑-4,5-二羧酸、四乙基氢氧化铵、1,10-菲罗啉和六水高氯酸锰在乙醇-水混合溶剂中反应得到的。在单斜晶系中结晶，空间群Cc为a = 24.8043(6)， b = 8.7973(2)， c = 24.2475(2) a， β = 118.844(1)°，V = 4634.6(2)A3, Z = 4。最值得注意的结构特征是两个反离子，即Et4N+和ClO4-在晶格中共晶。
Synthesis and Crystal Structure of Tetraethylammonium Tris(1,10-phenanthroline)manganese(II) triperchlorate (Et4N)[Mn(phen)3](ClO4)3
The title complex was serendipitously obtained by reacting imidazole-4,5-dicarboxylic acid, tetraethylammonium hydroxide, 1,10-phenanthroline, and manganese(II) perchlorate hexahydrate in ethanol-water mixed solvent. It crystallizes in the monoclinic system, space group Cc with a = 24.8043(6), b = 8.7973(2), c = 24.2475(2)A, β = 118.844(1)°, V = 4634.6(2)A3 and Z = 4. A most noteworthy structural feature is that two counterions, namely Et4N+ and ClO4- cocrystallize in the crystal lattice.
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