麦哲伦泥炭(Sphagnum magallanicum)作为合成染料的天然吸附剂

Luisa A Sepulveda-Cuevas, Elsa G Contreras-Villacura, Carolyn L Palma-Toloza
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引用次数: 15

摘要

【摘要】由于染料的合成来源在工业上的应用,消色是一个复杂的问题。本研究的目的是评估麦哲伦泥炭(Sphagnum magallanicum)作为纺织染料吸附剂的可行性,通过测量染料的吸附能力来确定泥炭的物理化学特性,并探索其所含的天然微生物的降解潜力。结果表明,泥炭的比表面积(BET)为144.3 m2 g-1,体积为60%的中孔和大孔。泥炭表面碱性优于酸性,达到中性的pH值约为3.1。碱性染料、酸性染料和活性染料的固液相平衡浓度均可由Langmuir模型解释;但前者的最大吸附量显著高于后者。当溶液pH低于pzpc时,酸性染料的吸收能力增加。分离出三种具有脱色能力的细菌菌落。综上所述,泥炭可成功用于纺织废水的脱毒处理。
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MAGELLAN PEAT (Sphagnum magallanicum) AS NATURAL ADSORBENT OF RECALCITRAN SYNTHETIC DYES
Turba magallanica (Sphagnum magallanicum) como adsorbente natural de colorantes sinteticos recalcitrantes ABSTRACT Colour abatement is a complex problem because the synthetic origin of the dyes used in the industry. The purpose of this study is to evaluate the feasibility of using Magellan peat (Sphagnum magallanicum) as an adsorbent of textile dyes, determining the physical- chemical characteristics of the peat by measuring the adsorptive capacity of the dyes as well as exploring the degrading potential of the native microorganisms they contain. The results obtained indicate that the peat has a specific surface area (BET) and a volume of 144.3 m2 g-1 and 60% of meso- and macropores, respectively. The basicity of the peat surface is superior to acidity and the pH in which the neutrality is reached is about 3.1. Equilibrium concentrations for the basic, acid and reactive dyes in the solid and liquid phases were appropriately interpreted by the Langmuir model; however the maximum adsorption capacities of the first ones were significantly higher. If the solution pH is lower to pzpc, the absorption capacity of the acid dyes increases. Three different bacteria colonies with decolourization capacity were isolated. In conclusion, results indicate that the peat may be successfully applied in the detoxification of textile effluents.
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