Euboea沉积铁镍矿床的成岩作用:基于层状硅酸盐矿物学的证据

Spyros Cheliotis-Chatzidimitriou, G. Christidis, I. Marantos
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摘要

采用XRD和SEM-EDS对希腊中部Euboea沉积Fe-Ni矿床中不同质地的样品进行了研究,探讨了层状硅酸盐之间的关系。该矿床以蒙脱石、堇青石、R0混合层绿泥石-蒙脱石和分块绿泥石共存为特征,显示出不平衡状态。认为绿泥石是该矿床中主要的含镍矿,是由蒙脱石(非蒙脱石,也可能是闪辉石)在成岩作用过程中经锆英石和R0 - Chl-Sme转化而成。本文首次报道了富铁二八面体蒙脱石在成岩作用过程中的绿泥化作用。
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Diagenesis of the Sedimentary Fe–Ni Deposits of Euboea: Evidence Based on Phyllosilicate Mineralogy
A set of samples with different textures from the sedimentary Fe–Ni deposits of Central Euboea, Greece, were studied with XRD and SEM-EDS to investigate the relationships between phyllosilicates present. The deposits are characterized by the coexistence of smectite, corrensite, R0 mixed-layer chlorite-smectite and discrete chlorite, which indicates disequilibrium conditions. It is suggested that chlorite, the main Ni-host in the deposits, formed by conversion of smectite (nontronite and possibly stevensite), via corrensite and R0 Chl-Sme during diagenesis. This is the first report for chloritization of Fe-rich dioctahedral smectite during diagenesis.
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