双甘氨酸氢溴化物单晶的合成、生长和表征

K. Pandurangan, S. Suresh
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引用次数: 14

摘要

采用慢蒸发法制备了BGHB单晶。通过单晶x射线衍射确定了生长晶体的单晶尺寸和空间群。利用FTIR技术鉴定了分子的振动模式和官能团的存在。显微硬度研究表明,晶体的维氏硬度值随外加载荷的增加而增加。用紫外-可见光谱法测定了晶体的光学性质。还测定了生长晶体的热性能。用布鲁斯特角法测定折射率为1.396。通过Nd: YAG激光发射的绿光证实了晶体的二次谐波产生特性,并且发现晶体的SHG效率高于KDP。在不同温度和频率下进行了介电常数和介电损耗测量。讨论了晶体的交流电导率研究。光电导率研究证实了生长的晶体具有负光电导率性质。为了研究腐蚀坑的形成,进行了腐蚀研究。
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Synthesis, Growth, and Characterization of Bisglycine Hydrobromide Single Crystal
Single crystals of BGHB were grown by slow evaporation technique. The unit cell dimensions and space group of the grown crystals were confirmed by single crystal X-ray diffraction. The modes of vibration of the molecules and the presence of functional groups were identified using FTIR technique. The microhardness study shows that the Vickers hardness number of the crystal increases with the increase in applied load. The optical properties of the crystals were determined using UV-Visible spectroscopy. The thermal properties of the grown crystal were also determined. The refractive index was determined as 1.396 using Brewster’s angle method. The emission of green light on passing the Nd: YAG laser light confirmed the second harmonic generation property of the crystals and the SHG efficiency of the crystals was found to be higher than that of KDP. The dielectric constant and dielectric loss measurements were carried out for different temperatures and frequencies. The ac conductivity study of the crystals was also discussed. The photoconductivity studies confirm that the grown crystal has negative photoconductivity nature. The etching studies were carried out to study the formation of etch pits.
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