纤维素/二氧化硅复合气凝胶制备方法研究

Chon-Hsin Lin, Ang Li, Yang Cao, Lingbin Lu
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引用次数: 3

摘要

纤维素气凝胶是一种具有高孔隙率、低密度和生物相容性的令人着迷的材料。然而,纤维素气凝胶缺乏足够的热稳定性。纤维素气凝胶与二氧化硅的复合可以有效地提高纤维素气凝胶的热稳定性。本研究以四乙氧基硅烷为硅源,氢氧化钠溶液为纤维素溶剂,采用滴法制备纤维素/二氧化硅复合气凝胶。结果表明,二氧化硅的引入提高了纤维素气凝胶的热稳定性。通过这种方法,二氧化硅的利用率可达95%。复合气凝胶具有低密度、高孔隙率的特点,具有良好的隔热性能,其导热系数低至0.0161W/(m·K)。此外,通过调节纤维素浓度和四乙氧基硅烷的用量,可以控制复合气凝胶的密度、孔隙率和导热系数。该工作有助于提高二氧化硅的利用效率,制备性能更好的复合气凝胶。
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A Simple and Efficient Approach to Cellulose/Silica Composite Aerogel with High Silica Utilization Efficiency
Cellulose aerogel is a fascinating material with high porosity, low density and biocompatibility. However, cellulose aerogel lacks sufficient thermal stability. Recombination between cellulose aerogel with silica is efficacious for enhance the cellulose aerogel’s thermal stability. This work described a simple and efficient approach to the cellulose/silica composite aerogel via a dropwise manner, using tetraethoxysilane as silicon source and NaOH solution as cellulose solvent. The result showed that the thermal stability of cellulose aerogel was enhanced by introducing silica. And by this manner, the utilization efficiency of silica was up to 95%. The composite aerogel had a low density and a high porosity, which promised the material a good heat insulation performance, and the thermal conductivity of the composite aerogel was low to 0.0161W/(m·K). Moreover, by adjusting cellulose concentration and tetraethoxysilane amount, the density, porosity and thermal conductivity of the composite aerogel could be controlled. This work contributed to improving the utilization efficiency of silica for the composite aerogel with better performances.
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