胺接枝功能化介孔二氧化硅纳米材料室内湿度控制特性的影响

IF 1 4区 工程技术 Q3 ENGINEERING, MULTIDISCIPLINARY Journal of the Chinese Institute of Engineers Pub Date : 2022-11-13 DOI:10.1080/02533839.2022.2141336
Ya‐Wen Lin, Wei-Hao Lee, Bo-Yi Kuo, Kae‐Long Lin
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引用次数: 1

摘要

摘要本研究提取了富含石泥的硅源和铝源,采用碱熔盐法确定了不同碱熔温度和碱剂配比下的最佳碱熔工艺。在材料表面用3-氨基丙基三乙氧基硅烷接枝,得到胺接枝官能团MCM-41材料(APTES/MCM-41)。对APTES/MCM-41材料进行了分析,并进行了水吸附/解吸实验。利用石泥制备的APTES/MCM-41具有较高的比表面积(25.19 m2/g),孔径可调,结构表面易于接枝,可以利用不同的官能团开发新材料。含2.5 vol.%胺官能团的APTES/MCM-41的24 h吸湿量为37.02 g/m2,符合JIS A 1470-1规范,远远超过湿度控制涂料中硅藻土和无机材料的吸湿量(18.6 g/m2)。APTES/MCM-41可用作机械除湿机的替代品。
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Effect of the indoor humidity control characteristics for amine grafted functionalized mesoporous silica nanomaterials
ABSTRACT In this study, the silicon source and aluminum source rich in stone mud were extracted, and the best alkali fusion process for different alkali fusion temperatures and alkali agent ratios was determined by the alkali fusion salt method. The surface of the material was grafted by 3-aminopropyltriethoxysilane to obtain an amine grafted functionalized groups MCM-41 material (APTES/MCM-41). The APTES/MCM-41 material was analyzed and water adsorption/desorption experiment was performed. Utilizing stone sludge to obtain APTES/MCM-41, which has a high specific surface area (25.19 m2/g) and, an adjustable pore size and an easy structural surface grafted can use different functional groups for the development of new materials. The 24-h moisture adsorption capacity of the APTES/MCM-41 with 2.5 vol.% amine functional groups was 37.02 g/m2, which conforms to JIS A 1470–1 specifications and far exceeds that of diatomaceous earth and inorganic materials in humidity control coatings (18.6 g/m2). APTES/MCM-41 could be used as an alternative to mechanical dehumidifiers.
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来源期刊
Journal of the Chinese Institute of Engineers
Journal of the Chinese Institute of Engineers 工程技术-工程:综合
CiteScore
2.30
自引率
9.10%
发文量
57
审稿时长
6.8 months
期刊介绍: Encompassing a wide range of engineering disciplines and industrial applications, JCIE includes the following topics: 1.Chemical engineering 2.Civil engineering 3.Computer engineering 4.Electrical engineering 5.Electronics 6.Mechanical engineering and fields related to the above.
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