异质结聚合物薄膜中的电输运

S. Rathi, Amarjeet Singh
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引用次数: 0

摘要

采用自旋镀膜技术合成了导电聚合物基异质结薄膜。研究了薄膜在80℃退火前后的电流-电压(I-V)特性。发现肖特基发射是薄膜的主要电荷转移机制。退火强烈影响I-V特性,表明由于热辅助相分离,内部形貌发生了强烈变化。计算了相对介电常数随外加电场和退火温度的变化。
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Electrical transport in heterojunction polymer films
Conducting polymer based heterojunction films were synthesized using spin coating technique. Current – Voltage (I-V) characteristics of the films were investigated before and after annealing up to 80°C. It was found that Schottky emission is main charge transfer mechanism observed for the films. Annealing strongly influences the I-V characteristics suggesting a strong change in internal morphology due to thermally assisted phase separation. The relative dielectric permittivity was calculated which depends on the applied field as well as annealing temperature.
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