{"title":"二维Mn(II)配位聚合物的合成、晶体结构和发光性能:连环-(二水-四akis(µ2-肉桂-o,o ')-锰(II))","authors":"Yin‐Qiu Liu","doi":"10.1080/15533174.2014.988823","DOIUrl":null,"url":null,"abstract":"A new manganese(II) complex: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II) was prepared by the method of solvothermal synthesis, and its two-dimensional coordination polymeric network was determined by X-ray diffraction. It crystallized in monoclinic, space group C2/c, with a = 36.934(14) Å, b = 6.468(2) Å, c = 7.435(3) Å, ß = 91.733(7)°, Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3. Under ultraviolet radiation of 338 nm the emissions of the title complex mainly result from its ligand: cinnamic acid.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Crystal Structure, and Luminescent Properties of a Two-Dimensional Mn(II) Coordination Polymer: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II))\",\"authors\":\"Yin‐Qiu Liu\",\"doi\":\"10.1080/15533174.2014.988823\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new manganese(II) complex: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II) was prepared by the method of solvothermal synthesis, and its two-dimensional coordination polymeric network was determined by X-ray diffraction. It crystallized in monoclinic, space group C2/c, with a = 36.934(14) Å, b = 6.468(2) Å, c = 7.435(3) Å, ß = 91.733(7)°, Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3. Under ultraviolet radiation of 338 nm the emissions of the title complex mainly result from its ligand: cinnamic acid.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2014.988823\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988823","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
采用溶剂热合成的方法制备了一种新的锰(II)配合物:Catena-(diaqua-tetrakis(µ2-cinnamato-o,o ')-锰(II)，并用x射线衍射测定了其二维配位聚合物网络。晶型为单斜晶，空间群为C2/c, a = 36.934(14) Å， b = 6.468(2) Å， c = 7.435(3) Å， ß = 91.733(7)°，Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3。在338nm的紫外辐射下，标题配合物的发光主要来自其配体肉桂酸。
Synthesis, Crystal Structure, and Luminescent Properties of a Two-Dimensional Mn(II) Coordination Polymer: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II))
A new manganese(II) complex: Catena-(diaqua-tetrakis(µ2-cinnamato-o,o′)-manganese(II) was prepared by the method of solvothermal synthesis, and its two-dimensional coordination polymeric network was determined by X-ray diffraction. It crystallized in monoclinic, space group C2/c, with a = 36.934(14) Å, b = 6.468(2) Å, c = 7.435(3) Å, ß = 91.733(7)°, Z = 4, Dc = 1.441 Mg/m3, V = 1775.2(11) Å3. Under ultraviolet radiation of 338 nm the emissions of the title complex mainly result from its ligand: cinnamic acid.
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