果壳生物吸附剂的制备及性能研究

Kartel Mykola, G. Vita, W. Bo, Mukalo Yevgen, Kozakevych Roman, Nikolaichuk Alina
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摘要

研究了在“醋酸-过氧化氢”介质中氧化-有机溶剂法处理杏壳制备新型生物吸附剂的工艺。研究了用物理和化学方法制备的材料的结构和吸附性能。考察了溶液中反应物配比、改性时间对产物收率、纤维素、木质素、矿物组分含量及吸附性能的影响。结果表明,矿物含量与吸附孔体积之间存在相关性。评价了过氧化氢在植物废料改性过程中对纤维素含量的积极影响。延长改性时间增加了木质素氧化转化为可溶性产物的贡献,降低了木质纤维素材料的收率。考察了低分子量毒素和非甾体类抗炎药标记物在所得产品上的吸附规律。结果表明,当多糖含量为60%时,木质纤维素吸附剂对亚甲基蓝和双氯芬酸钠的吸附量最高。还发现吸附平衡在接触后120分钟内发生。研究结果表明,这种木质纤维素载体在长效药物生产中的应用是可行的。
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Preparation and Properties of Biosorbents on the Base of Fruit Seed Shell
The process of obtaining of new biosorbents from apricot seed shells by oxidative-organosolvent processing in "acetic acid - hydrogen peroxide" medium has been studied. The structural and sorption properties of the materials obtained using physical and chemical methods were investigated. The effect of the reactants ratio in solution, as well as the duration of the modification process on the yield, content of cellulose, lignin, and mineral components and on sorption properties of the products was studied. The dependence between the mineral content and the adsorption pore volume was shown. The positive effect of hydrogen peroxide application in the process of modifying of plant waste on cellulose content was estimated. Increasing the duration of modification increases the contribution of oxidative transformation of lignin into soluble products and decreases the yield of the lignocelluloses’ materials. The regularities of sorption of marker of low molecular weight toxins and non-steroidal anti-inflammatory drugs on obtained products were investigated. It has been found that the highest sorption capacity of obtained lignocelluloses’ sorbents towards methylene blue and Sodium Diclofenac corresponds to the samples with polysaccharide content 60%. It has been also found that the sorption equilibrium occurs within 120 min of contact. The obtained results demonstrate the feasibility of application of such lignocelluloses’ carriers in the production of prolonged action drugs.
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