Δ-Cadinene的硫醇和硫乙酸酯衍生物

Sulfur Letters Pub Date : 2002-01-01 DOI:10.1080/02786110210631

Karine Candela, R. Fellous, D. Joulain, R. Faure

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引用次数: 2

摘要

(s−)- i -cadinene 1的光化学硫乙酰化得到5-乙酰基硫代cadinene 1a，进一步还原为5-巯基cadinene 1b，收率很高(80%)。研究了以m -CPBA氧化1制备的反式-1,10-二苯二烯氧化物1c的硫代环氧化反应。这些衍生物的结构测定是通过一维和二维核磁共振波谱实现的。

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Thiol and Thioacetate Derivatives of Δ-Cadinene

Photochemical thioacetylation of (s−)- i -cadinene 1 afforded 5-acetylthio-cadinene 1a which was further reduced into 5-mercapto-cadinene 1b in good yield (80%). Thioepoxydation of trans -1,10-cadinene oxide 1c , prepared from m -CPBA oxidation of 1 , was also investigated. Structural determination of these derivatives was achieved by one- and two dimensional NMR spectroscopy.

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Sulfur Letters

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