聚酰胺膜对水中各种盐离子的选择性萃取机理研究

А.М. Azimov, B.M. Smaiylov, C. T. Aravindkumar, U. Aravind
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引用次数: 0

摘要

膜分离浓缩过程属于海水淡化用结构和功能材料的获取和加工的关键技术范畴。通过对膜分离动力学的分析,确定了聚酰胺膜的发展前景和优势,聚酰胺膜对所研究的盐溶液具有一定的抗性。研究聚酰胺膜选择性提取水中盐离子的机理特点和规律。利用聚酰胺膜对水中盐离子的选择性提取是水净化的重要方法。方法。聚酰胺对盐有很高的选择性,但通过它们的水流略低。在pH值2.0 - 10的范围内,聚酰胺可以承受高达100℃的加工温度而不会显著改变多孔结构,允许多次再生,并且可以抵抗大多数酸,具体取决于介质的pH值。结果。根据利用聚酰胺膜从水中提取盐离子的中试结果,发现在pH = 6-7的区域,假定盐离子的主要带电形式共同存在。结论。由此可见,pH = 6.5-7.5时,孔半径为5 ~ 8nm的膜中盐离子的扩散系数值与盐离子的扩散系数大致相当。
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INVESTIGATION OF THE MECHANISM OF SELECTIVE EXTRACTION OF IONS OF VARIOUS SALTS FROM WATER, USING POLYAMIDE MEMBRANES
The processes of membrane separation and concentration belong to the category of critical technologies for obtaining and processing structural and functional materials for desalination of water. The prospects and advantages of polyamides membranes are determined based on the analysis of the kinetics of membrane separation, the polyamides membrane has resistance to the studied salt solutions. The purpose of this work is to study the features and regularities of the mechanism of selective extraction of salt ions from water by polyamide membranes. Great importance are the methods of water purification in the selective extraction of salt ions from water using polyamide membranes. Methodology. Polyamides have a high selectivity with respect to salts, but the flow of water through them is slightly lower. At a pH range 2.0 – 10 polyamides, they withstand processing temperatures up to 100 0C without significant changes in the porous structure, allow multiple regeneration, and are resistant to most acids, depending on the pH of the medium. Results. According to the results of pilot tests in the extraction of salt ions from water using polyamide membranes, it was found that in the pH region = 6-7, the joint presence of the main charged forms of salt ions is assumed. Conclusion. Thus, based on the results, it follows that the values of the diffusion coefficients of salt ions in membranes with pore radii from 5 to 8 nm at pH =6.5–7.5 are generally comparable for salt ions.
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