沸石对氟化物的吸附能力及影响因素研究

Sun Xingbin, Xi Chengju, Hou Zhaochao
{"title":"沸石对氟化物的吸附能力及影响因素研究","authors":"Sun Xingbin, Xi Chengju, Hou Zhaochao","doi":"10.1109/CESCE.2010.59","DOIUrl":null,"url":null,"abstract":"In modification experiment the best modification method was established. First, natural zeolite was roasted at 600¿ in a muffle furnace for 2h. After cooled to normal temperature, it was soaked in 4% HCl solution on dynamic condition at 65¿ for 1 hour, then soaked in 1mol/L NaOH solution on dynamic condition at 40¿ for 1 hour. The preconditioned zeolite was then was soaked in 10%AlCl3 solution on dynamic condition at 40¿ for 20 hour. In the end, it was treated in water vapour for 1 hour. Static experiment was carried out in order to examine defluorination ability of modified zeolite. The results showed that the adsorption capacity of zeolite was greatly enhanced after being modified, which obtained 0.25mg/g for fluoride solution with 20mg/L concentration. There were many factors affecting the adsorption capacity of modified zeolite. Among all the factors, the pH value and concentration of raw water and the running speed in dynamic experiment had greater influence. The structures of natural zeolite and modified zeolite were observed by SEM, XRD and FT-IR. Based on these, the reason and effect of modification were further analyzed.","PeriodicalId":6371,"journal":{"name":"2010 International Conference on Challenges in Environmental Science and Computer Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2010-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The Fluoride-adsorption Capacity and Influencing Factors Study of Zeolite\",\"authors\":\"Sun Xingbin, Xi Chengju, Hou Zhaochao\",\"doi\":\"10.1109/CESCE.2010.59\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In modification experiment the best modification method was established. First, natural zeolite was roasted at 600¿ in a muffle furnace for 2h. After cooled to normal temperature, it was soaked in 4% HCl solution on dynamic condition at 65¿ for 1 hour, then soaked in 1mol/L NaOH solution on dynamic condition at 40¿ for 1 hour. The preconditioned zeolite was then was soaked in 10%AlCl3 solution on dynamic condition at 40¿ for 20 hour. In the end, it was treated in water vapour for 1 hour. Static experiment was carried out in order to examine defluorination ability of modified zeolite. The results showed that the adsorption capacity of zeolite was greatly enhanced after being modified, which obtained 0.25mg/g for fluoride solution with 20mg/L concentration. There were many factors affecting the adsorption capacity of modified zeolite. Among all the factors, the pH value and concentration of raw water and the running speed in dynamic experiment had greater influence. The structures of natural zeolite and modified zeolite were observed by SEM, XRD and FT-IR. Based on these, the reason and effect of modification were further analyzed.\",\"PeriodicalId\":6371,\"journal\":{\"name\":\"2010 International Conference on Challenges in Environmental Science and Computer Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2010-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2010 International Conference on Challenges in Environmental Science and Computer Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/CESCE.2010.59\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2010 International Conference on Challenges in Environmental Science and Computer Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/CESCE.2010.59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3

摘要

在改性试验中,确定了最佳改性方法。首先,将天然沸石在马弗炉中以600℃的温度焙烧2h。冷却至常温后,在4% HCl溶液中65℃动态浸泡1小时,再在1mol/L NaOH溶液中40℃动态浸泡1小时。然后将预处理好的沸石在10%AlCl3溶液中,在40℃下动态浸泡20小时。最后,在水蒸气中处理1小时。为考察改性沸石的除氟能力,进行了静态实验。结果表明,改性后的沸石吸附量大大提高,对浓度为20mg/L的氟溶液吸附量达到0.25mg/g。影响改性沸石吸附性能的因素很多。其中,原水pH值、原水浓度和动态实验运行速度的影响较大。采用扫描电镜(SEM)、x射线衍射(XRD)和红外光谱(FT-IR)对天然沸石和改性沸石的结构进行了观察。在此基础上,进一步分析了改性的原因和效果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
The Fluoride-adsorption Capacity and Influencing Factors Study of Zeolite
In modification experiment the best modification method was established. First, natural zeolite was roasted at 600¿ in a muffle furnace for 2h. After cooled to normal temperature, it was soaked in 4% HCl solution on dynamic condition at 65¿ for 1 hour, then soaked in 1mol/L NaOH solution on dynamic condition at 40¿ for 1 hour. The preconditioned zeolite was then was soaked in 10%AlCl3 solution on dynamic condition at 40¿ for 20 hour. In the end, it was treated in water vapour for 1 hour. Static experiment was carried out in order to examine defluorination ability of modified zeolite. The results showed that the adsorption capacity of zeolite was greatly enhanced after being modified, which obtained 0.25mg/g for fluoride solution with 20mg/L concentration. There were many factors affecting the adsorption capacity of modified zeolite. Among all the factors, the pH value and concentration of raw water and the running speed in dynamic experiment had greater influence. The structures of natural zeolite and modified zeolite were observed by SEM, XRD and FT-IR. Based on these, the reason and effect of modification were further analyzed.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Recent Advances in Managed Aquifer Recharge in China Minimum Attribute Number in Decision Table Based on Maximum Entropy Principle A Security Architecture for Wireless Mesh Network The Research of K-means Clustering Algorithm Based on Association Rules Improving the Identification of Business Components: A Framework Based on Knowledge Management of Process Illustrating
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1