某矿山废石酸、金属排水电位的测定

S. Fosu, C. Owusu, F. Ntsiful, K. Ackah
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摘要

酸和金属排放(AMD)是公认的采矿行业严重的环境问题。这是因为AMD的环境问题对水质、植被覆盖和采矿作业的社会许可构成了严重威胁。当含有活性硫化物的材料暴露在氧化条件下时,AMD就会发生。现在,一些矿业公司必须在进行重大采矿挖掘之前测试含硫化物矿物的AMD潜力。这项工作确定了50(50)废石样品的AMD潜力从一个矿山使用酸碱核算(ABA)技术。样品的矿物学研究表明,硫化物矿物组合主要为黄铁矿、毒砂和黄铜矿。膏体pH值表明,20%的样品经历了风化,因此AMD的生成已经开始。大约22%的样品的电导率水平在1000到10,000µS/cm之间,这显示了典型的高盐度AMD化学特征。酸碱计算表明,32%的样品产生酸。16%为非酸形成,52%为不确定。分析表明,废石料存在产生AMD的潜力,如果不采取预防措施,可能会影响当地环境,特别是水质。关键词:硫化物,废石,酸碱核算,膏体pH,电导率
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Determining Acid and Metalliferous Drainage Potential of Waste Rock on a Mine
Acid and Metalliferous Drainage (AMD) is recognised as serious environmental problem in the mining industry. This is because environmental issue of AMD poses serious threat to water quality, vegetation cover and social licence of the mining operations. AMD occurs when reactive sulphide bearing materials are exposed to oxidising conditions. It has now become imperative for some mining companies to test sulphide bearing minerals for their AMD potential before major mining excavations are done. This work determines the AMD potential of fifty (50) waste rock samples from a Mine using Acid Base Accounting (ABA) techniques. Mineralogical studies on the sample indicated that the major sulphide mineral assemblages present were pyrite, arsenopyrite and chalcopyrite. Paste pH showed that 20% of the samples had undergone weathering and as such AMD generation had already started. Approximately 22% of the sample had conductivity levels between 1000 to 10,000 µS/cm and this shows a typical AMD chemical characteristic of high salinity. Acid Base Accounting showed that 32% of the samples were acid generating. Exactly 16% were non-acid forming and 52% were uncertain. The analysis showed that the potential for AMD generation exists for the waste rock material and can affect the local environment, specifically water quality if preventive measures are not taken.   Keywords: Sulphide, Waste Rock, Acid Base Accounting, Paste pH, Conductivity
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