{"title":"轨道控制:一个不必要的概念","authors":"B. Capon","doi":"10.1039/J29710001207","DOIUrl":null,"url":null,"abstract":"It is shown that it is not justifiable to invoke ‘orbital steering’ to explain the variation in the rates of lactonisation of the hydroxy-acids studied by Storm and Koshland.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"15 1","pages":"1207-1209"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Orbital steering: an unnecessary concept\",\"authors\":\"B. Capon\",\"doi\":\"10.1039/J29710001207\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"It is shown that it is not justifiable to invoke ‘orbital steering’ to explain the variation in the rates of lactonisation of the hydroxy-acids studied by Storm and Koshland.\",\"PeriodicalId\":17268,\"journal\":{\"name\":\"Journal of The Chemical Society B: Physical Organic\",\"volume\":\"15 1\",\"pages\":\"1207-1209\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society B: Physical Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J29710001207\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710001207","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
It is shown that it is not justifiable to invoke ‘orbital steering’ to explain the variation in the rates of lactonisation of the hydroxy-acids studied by Storm and Koshland.