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引用次数: 16

摘要

讨论了链烷、结分子和博罗米安环的立体化学。提出了对Cahn-Ingold-Prelog约定的一种扩充,用于指定绝对构型。提出了一种确定打结分子绝对构型的惯例。对分子不对称非对映体绝对构型的引用提出了建议。
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Absolute Configuration and Chemical Topology
The stereochemistry of catenanes, knotted molecules, and Borromean rings is discussed. An augmentation of the Cahn-Ingold-Prelog convention for designating absolute configuration is proposed. A convention is proposed for designating the absolute configuration of knotted molecules. A suggestion is made concerning the citing of the absolute configuration of molecularly dissymmetric diastereomers.
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