本土微生物衍生生物吸附剂在高效去除刚果红中的潜在应用

Lalmalsawm dawngliani, Gospel Lallawmzuali, Samuel Lallianrawna, T. liana, K. Vanlaldinpuia, C. Lalhriatpuia
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引用次数: 0

摘要

以厨余生物质为原料,以原生微生物(IMO)为孕育剂,通过厌氧发酵工艺制备IMO堆肥。通过测定固体的pH、MC、OM、OC、N、K、P含量,得到固体的理化分析结果。利用扫描电镜、红外光谱和BET分析技术对生物吸附材料进行了表征。在使用IMO堆肥去除刚果红(CR)染料时,进行了各种物理化学参数研究,即pH值、初始染料浓度和背景电解质浓度的影响。较低的pH条件下,pH < 6.0有利于刚果红的去除率,去除率随CR浓度的增加而降低。刚果红的去除符合准二级速率动力学,平衡态吸附数据符合Freundlich吸附等温线。此外,背景电解质浓度(0.0001至0.1 mol/L NaNO3)对CR去除的影响最小,这表明在生物吸附剂表面形成“内球”复合物的刚果红特异性吸附。
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Potential Application of Indigenous Microorganism Derived Biosorbent in the Efficient Removal of Congo Red from Aqueous Solution
IMO compost was obtained using Indigenous Microorganisms (IMO) as inoculant through anaerobic fermentation process from kitchen waste biomass. The Physico-chemical analysis of the solid was obtained by taking pH, MC, OM, OC, N, K and P content. The biosorbent material was further characterized by SEM, IR and BET analytical techniques. Various physico-chemical parametric studies viz. effect of pH, initial dye concentration and background electrolyte concentrations are performed in the removal of Congo red (CR) dye using the IMO compost. The lower pH condition pH < 6.0 favoured the removal of Congo red and the percent removal was decreased with increase in the CR concentration. The removal of Congo red followed the pseudo-second order rate kinetics and the equilibrium state sorption data was reasonably fitted well to the Freundlich adsorption isotherm. In addition, the minimal effect of background electrolyte concentrations (0.0001 to 0.1 mol/L NaNO3) in the removal of CR inferred a specific sorption of Congo red forming ‘inner sphere’ complexes at the surface of the biosorbent.
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