纳米二氧化硅砂对环氧基复合材料的影响研究

T. Ahmad, O. Mamat, R. Ahmad
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引用次数: 42

摘要

制备亚微米无机粒子的研究在过去的十年中一直处于主导地位,现在正在制备纳米填料增强的聚合物基复合材料(PMC)。本研究的目的是研究纳米二氧化硅在环氧树脂中的增强分散体对复合材料的物理性能、力学和热行为以及微观结构的改性作用。将硅砂纳米颗粒(在我们早期的研究中开发)(Ahmad和Mamat, 2012)手动混合到环氧树脂中,然后采用搅拌混合的方法进行固化,从而开发出纳米复合材料。实验值表明:15wt。纳米硅砂的加入提高了复合材料的杨氏模量;然而,拉伸强度的降低也被观察到。由于搅拌不当而产生的孔洞和空腔是影响材料力学性能的主要原因。在差示扫描量热法(DSC)分析中观察到,硅砂纳米颗粒的加入导致纳米复合材料结晶度的降低。
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Studying the Effects of Adding Silica Sand Nanoparticles on Epoxy Based Composites
The research about the preparation of submicron inorganic particles, once conducted in the past decade, is now leading to prepare polymer matrix composite (PMC) reinforced with nanofillers. The objective of present research is to study the modified effects of reinforcement dispersion of nanoparticle silica in epoxy resin on the physical properties, mechanical and thermal behaviour, and the microstructure of resultant composites. Stirrer mixing associated with manual mixing of silica sand nanoparticles (developed in our earlier research) (Ahmad and Mamat, 2012) into epoxy was followed by curing being the adopted technique to develop the subject nanocomposites. Experimental values showed that 15 wt.% addition of silica sand nanoparticles improves Young’s modulus of the composites; however, a reduction in tensile strength was also observed. Number of holes and cavities produced due to improper mixing turn out to be the main cause of effected mechanical properties. Addition of silica sand nanoparticles causes a reduction in degree of crystallinity of the nanocomposites as being observed in differential scanning calorimetry (DSC) analysis.
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