溴化氢、氯化氢和水中的电荷转移反应

A. Jówko, M. Foryś, B.Ö. Jonsson
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引用次数: 4

摘要

得到了几种反应物离子对氯化氢、溴化氢和水蒸气的电荷转移的相对截面以及HBr的质谱。Q(RE)函数与相应的光电子能谱相似,证实了先前关于PE峰可以作为实验FC因子的陈述。电子和/或振动激发以及反应物离子的动能对溴化氢质谱的影响已经得到证明。
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Charge transfer reactions in hydrogen bromide, hydrogen chloride and water

The relative cross-sections for charge transfer to hydrogen chloride, hydrogen bromide and water vapour together with the mass spectrum of HBr were obtained with several reactant ions.

The Q(RE) functions resembled the corresponding photoelectron spectra, confirming earlier statements that the PE peaks can be treated as experimental FC factors.

The influence of electronic and/or vibrational excitation, as well as of the kinetic energy of the reactant ions, on the hydrogen bromide mass spectrum has been demonstrated.

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Editorial Subject index Author index High resolution accurate mass measurements of FAB-generated ions by use of peak matching and multichannel analyzer techniques. Secondary ion mass spectrometry of low-temperature solids
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