以烯烃复分解为关键步骤合成氧-三醌的方法

IF 0.5 4区化学 Q3 Pharmacology, Toxicology and Pharmaceutics Indian Journal of Chemistry Section B-organic Chemistry Including Medicinal Chemistry Pub Date : 2020-12-16 DOI:10.56042/ijcb.v59i12.40244

S. Kotha, Sunil Pulletikurti

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引用次数: 0

摘要

在此之前，已经证明了一种由外酸酐通过复分解合成顺式、顺式、顺式三醌和丙烷的简单方法。在目前的工作中，讨论了一个独特的观察过程，当这种方法已扩展到氧合的外酸酐衍生物，并证明了立体化学的重要性和杂原子在烯烃复分解结果中的作用。

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Synthetic approach to oxa-triquinanes via olefin metathesis as a key step

Earlier, a simple synthetic approach to cis , syn , cis- triquinanes and propellanes from exo -nadic anhydride through metathesis approach had been demonstrated. In the present work is discussed a distinct course of observations when this methodology has been extended to oxygenated exo -nadic anhydride derivatives and the importance of stereochemistry and the role of hetero atom in the outcome of olefin metathesis has been demonstrated.

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来源期刊

Indian Journal of Chemistry Section B-organic Chemistry Including Medicinal Chemistry 化学-有机化学

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0.00%

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审稿时长

4-8 weeks

期刊介绍： Indian Journal of Chemistry (Section B) is a leading monthly journal in Organic and Medicinal Chemistry started publishing from 1976. It publishes papers on organic reaction mechanism, theoretical organic chemistry, structure-activity relationships, medicinal chemistry, synthesis of chiral compounds, bio-organic chemistry, enzymes in organic synthesis, reagents in organic synthesis, heterocyclic compounds, phytochemistry (natural products), amino acids, peptides and proteins, spectroscopy in characterization of organic compounds, chemoenzymatic and enantioselective synthesis of organic compounds, synthesis of fullerenes, metal-catalyzed asymmetric reactions, bioactive plant products and combinatorial chemistry. Apart from full length papers, notes and communications, the journal publishes short reviews on frontline areas under the column " advances in Contemporary Research".