聚苯胺-聚氯乙烯共混物的研究

M. Chipara, I. Munteanu, P. Notingher, M. Chipara, J. Reyes Romero, B. Negreanu, D. Panaitescu
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引用次数: 1

摘要

在这篇文章中,我们将以前对聚苯胺共混物的研究扩展到对不同聚苯胺聚氯乙烯(PANI-PVC)共混物的一些物理性质的研究。先前关于聚苯胺-聚乙烯(PANI- pe)共混物的数据表明,随着聚苯胺(PANI)浓度的增加,共混物的机械特性迅速下降,而电导率的增加相对缓慢。由于共混物是通过组分的机械混合制备的,电导率随着时间的推移而降低,这可能是由于共混物对氧的稳定,同时导电聚苯胺(祖母绿盐)转变为聚苯胺的绝缘形式。
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On polyaniline-polyvinylchloride blends
In this contribution we extend our previous studies on polyaniline blends to the study of some physical properties of different polyaniline polyvinylchloride (PANI-PVC) blends. Previous data on polyaniline-polyethylene (PANI-PE) blends have revealed a rapid drop of the mechanical features of the blend, as the concentration of polyaniline (PANI) is increased and a relatively slow increase in the electrical conductivity. As the blend has been prepared by mechanical mixing of components, the electrical conductivity decreases in time, probably due to a stabilisation of the blend towards oxygen accompanied by the transformation of the conducting polyaniline (emeraldine salt) into the insulating form of the polyaniline.
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