光电用Pb:Zr:/O2纳米棒的合成与表征研究

K. Kaviyarasu, X. Fuku, L. Kotsedi, Manik, E. an, J. Kennedy, M. Maaza
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引用次数: 8

摘要

本文以水合硝酸锆(Zr(NO3)4.5H2O)和硝酸铅(Pb(NO3)2)为前驱体,采用水热法制备了ZrO2掺杂PbO2纳米晶。实验结果表明,碘(I)的量和NaOH浓度对900℃下21小时内六边形乙二醇的生成有重要影响。采用x射线衍射(XRD)、紫外可见光谱(UV-vis)、傅里叶变换红外光谱(FTIR)和透射电子显微镜(TEM)对Zr掺杂氧化铅纳米棒的理化性质进行了表征。在紫外光和可见光照射下,Zr掺杂的氧化铅纳米棒的光子活性最高。
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Synthesis and Characterization Studies of Pb:Zr:/O2 Nanorods for Optoelectronic Applications
Synthesis and Characterization Studies of Pb:Zr:/O2 Nanorods for Optoelectronic Applications In the present work, we have synthesized ZrO2 doped PbO2 nanocrystals were successfully prepared by hydrothermal method which is Zirconium nitrate hydrate (Zr(NO3)4.5H2O) and lead nitrate (Pb(NO3)2) were used as a precursor. In the experimental results show that the amount of Iodine (I) and the NaOH concentration plays a important roles in the formation of hexagonal defined amount of ethylene glycol at 900 °C within 21 hrs. In the physiochemical properties of Zr doped lead oxide nanorod were determined by using X-ray diffraction (XRD), ultraviolet–visible spectroscopy (UV-vis), Fourier Transform Infrared spectroscopy (FTIR) and Transmission electron microscope (TEM). In Zr doped Pb oxide nanorods were the highest photon activity under both UV and visible light irradiation.
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