利用机械化学活化藻类从(bansk Hodruša,斯洛伐克)精矿中获得纳米金

J. Ficeriová, E. Dutková, J. Harvanová
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摘要

处理含金量低的硫化物精矿的困难和主要毒性促使人们发现了一种更有效和更环保的方法来获得这种贵金属。因此,这项工作的重点是从难熔硫化物络合物(bansk Hodruša,斯洛伐克)的精矿中利用非氰化物机械化学-生物过程回收金。该复杂精矿中的金在物理上位于硫化矿物的晶间空间,并填充在硫化物的结构缺陷中。从精矿的复杂矿物基质中金的沉淀可以通过机械-化学-生物过程来实现。这种创新的工艺使得通过应用硫脲溶液来回收金成为可能,硫脲溶液是毒性氰化的首选替代品。生物工艺与藻类的应用表明,具有硅质结构的藻类可以从纳米尺寸的复杂精矿(bansk Hodruša,斯洛伐克)中获得金。沼泽藻(硅藻、金藻)是水生生态系统的一部分,是地球上所有植物中生物量最大的。机械化学生物工艺是一种从难熔硫化物精矿中获得100纳米金纳米颗粒的方法(bansk Hodruša,斯洛伐克)。
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Obtaining of Nano Gold from Concentrate (Banská Hodruša, Slovakia) Using Algae with Utilization of Mechanochemical Activation
The difficult and predominantly toxic processing of sulphide concentrates with a low gold content has prompted the finding of a more efficient and environmentally friendly method of obtaining this noble metal. This work was therefore focused on the recovery of gold from the concentrate of refractory sulphide complex (Banská Hodruša, Slovakia) using a non-cyanide mechanochemico-biological process. Gold in this complex concentrate is physically located in the intercrystalline space of sulfide minerals and fills in structural defects in sulfides. The precipitation of gold from the complex mineral matrices of the concentrate can be achieved using a mechanochemico-biological process. This innovative process makes it possible to recover gold by applying a thiourea solution, which is a preferred alternative to toxic a cyanidation. The use of a biological process with the application of algae has shown that algae with siliceous structures make it possible to obtain gold from a complex concentrate (Banská Hodruša, Slovakia) with dimensions of the nano. Limnetic algae (diatoms, golden algae) are part of aquatic ecosystems and form the largest of biomass of all plants on Earth. Mechanochemicobiological process is a method that allows to obtain 100 nm gold nanoparticles from refractory sulphide concentrate (Banská Hodruša, Slovakia).
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