孔雀石绿染料的高级氧化全矿化研究

IF 0.4 Q4 CHEMISTRY, MULTIDISCIPLINARY Acta Chemica Iasi Pub Date : 2018-12-01 DOI:10.2478/achi-2018-0017
Diana-Carmen Mirila, Mădălina-Ștefania Pîrvan, Nicoleta Platon, Ana-Maria Georgescu, V. Zichil, I. Nistor
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引用次数: 5

摘要

摘要本文研究了用离子交换法制备的蒙脱土(P1-PILCs)作为阳离子催化剂,对食品和纺织工业用有机染料孔雀石绿(MG)进行深度分解。用BET、FTIR和XRD对所得材料进行了表征。研究了催化剂用量、催化剂/臭氧用量、臭氧化时间和pH对合成染料矿化的影响,确定了最佳实验条件。与简单的臭氧化反应相比,催化剂的引入大大缩短了反应时间,收率从110分钟减少到几秒,达到95%以上。
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Total Mineralization of Malachite Green Dye by Advanced Oxidation Processes
Abstract In this work, the advanced decomposition of organic dyestuffs used in food and textile industry, such as Malachite Green (MG), was investigated in the presence of a cationic catalyst montmorillonite (P1-PILCs) prepared by ion-exchange method. The obtained material was characterized by BET, FTIR and XRD. The effects of different variables such as: catalyst dose, catalyst/ozone dose, ozonation time and the pH on the mineralization of the synthetic dye were studied and optimal experimental conditions were ascertained. Compared with simple ozonation, the introduction of the catalyst greatly reduces the duration of the process to reach over 95% yield from 110 minutes to some seconds.
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Acta Chemica Iasi
Acta Chemica Iasi CHEMISTRY, MULTIDISCIPLINARY-
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