{"title":"一些五坐标[Cu(bpy)2C1]Y配合物的结构轮廓","authors":"David Harrison, Declan Kennedy, Brian Hathaway ∗","doi":"10.1016/0020-1650(81)80033-5","DOIUrl":null,"url":null,"abstract":"<div><p>The structures of five cation distortion isomers of the five-coordinate [Cu(bpy)<sub>2</sub>Cl]<sup>+</sup> cation range from trigonal bipyramidal to square pyramidal distorted trigonal bipyramidal, restricted by the bite of the 2,2′-bipyridyl ligands. The structures may be related by a structural profile involving a linear combination of the <em>ν</em><sub>7</sub> and <em>ν</em><sub>8</sub> modes of vibration of a trigonal bipyramidal CuN<sub>2</sub>N<sub>2</sub>'Cl chromophore in C<sub>2V</sub> symmetry.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80033-5","citationCount":"11","resultStr":"{\"title\":\"A structural profile of some five-coordinate [Cu(bpy)2C1]Y complexes\",\"authors\":\"David Harrison, Declan Kennedy, Brian Hathaway ∗\",\"doi\":\"10.1016/0020-1650(81)80033-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The structures of five cation distortion isomers of the five-coordinate [Cu(bpy)<sub>2</sub>Cl]<sup>+</sup> cation range from trigonal bipyramidal to square pyramidal distorted trigonal bipyramidal, restricted by the bite of the 2,2′-bipyridyl ligands. The structures may be related by a structural profile involving a linear combination of the <em>ν</em><sub>7</sub> and <em>ν</em><sub>8</sub> modes of vibration of a trigonal bipyramidal CuN<sub>2</sub>N<sub>2</sub>'Cl chromophore in C<sub>2V</sub> symmetry.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80033-5\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800335\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800335","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A structural profile of some five-coordinate [Cu(bpy)2C1]Y complexes
The structures of five cation distortion isomers of the five-coordinate [Cu(bpy)2Cl]+ cation range from trigonal bipyramidal to square pyramidal distorted trigonal bipyramidal, restricted by the bite of the 2,2′-bipyridyl ligands. The structures may be related by a structural profile involving a linear combination of the ν7 and ν8 modes of vibration of a trigonal bipyramidal CuN2N2'Cl chromophore in C2V symmetry.
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